ATAR Notes: Forum
VCE Stuff => VCE Science => VCE Mathematics/Science/Technology => VCE Subjects + Help => VCE Chemistry => Topic started by: monokekie on November 11, 2009, 12:47:10 pm
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in the lead acid accumulator, which ions in the electrolyte of the batery would haave a net migrant towards the positive electrode??
:) thanks for your help
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Discharge:
Anode (negative) -  + SO_4^{2-}(aq) \to PbSO_4 (s) + 2e)
Cathode (positive) -  + 4H^+(aq) + SO_4^{2-}(aq) + 2e \to PbSO_4 (s) + 2H_2O(l))
You can see here that sulfate ions migrate to both electrodes (no net migration), while H+ only migrate towards the positive electrode.
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xie xie la, this is a question from stav09 question 6 C, the answer says it is negatively charged sulfate.
mmm. so i think the answer is wrong..
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Does the net migration occur because they are reactants at these electrodes, or is it to balance charge out like a salt bridge (anions to anode, cations to cathode?)
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xie xie la, this is a question from stav09 question 6 C, the answer says it is negatively charged sulfate.
mmm. so i think the answer is wrong..
Yeah it is wrong. Should be H+
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Does the net migration occur because they are reactants at these electrodes, or is it to balance charge out like a salt bridge (anions to anode, cations to cathode?)
Because they are reactants, they are being consumed at one end.
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no the answer is correct i discussed this with my teahcer today, cathode has a positive charge hence the negativer sulfate ions migrate to it,
the H2SO4 isnt a salt bridge, so the whole anions to the anode, cations to the cathode doesnt apply, because it is the elecrolyte
the SO4 ion have a NET migration to the postive electrode...this still means they are found at anode and can participate in that reaction
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no the answer is correct i discussed this with my teahcer today, cathode has a positive charge hence the negativer sulfate ions migrate to it,
the H2SO4 isnt a salt bridge, so the whole anions to the anode, cations to the cathode doesnt apply, because it is the elecrolyte
the SO4 ion have a NET migration to the postive electrode...this still means they are found at anode and can participate in that reaction
um okay.. thanks! but i don't see why is H+ incorrect?