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Archived Discussion => 2009 => End-of-year exams => Exam Discussion => Victoria => Chemistry => Topic started by: magnum on November 12, 2009, 12:41:31 pm

Title: Chemistry Unit 4 Exam Discussion
Post by: magnum on November 12, 2009, 12:41:31 pm

How did everyone find the Unit 4 exam?  ???


Title: Re: Chemistry Unit 4 Exam Discussion
Post by: kenny17 on November 12, 2009, 12:43:04 pm
easier than unit 3
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: angelboykevin on November 12, 2009, 12:46:41 pm
lol,, never ever ever ever did so good for chem!!!^^
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: TheJosh on November 12, 2009, 12:48:42 pm
lol,, never ever ever ever did so good for chem!!!^^

true dat 8-)
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: tommyk221 on November 12, 2009, 12:50:51 pm
easier than unit 3

agreed, easier than unit 3.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Squida on November 12, 2009, 12:51:48 pm
lol chem doesn't deserve a board
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: kdgamz on November 12, 2009, 12:52:07 pm
easier than unit 3

it had to be easier than the midyear
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: THem on November 12, 2009, 12:53:15 pm
lol chem doesn't deserve a board

Coz chems super fkn boring
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: crappy on November 12, 2009, 12:57:32 pm
wow that was a great exam. Much better than unit 3. and to top it all off, that was my last exam!!!!!!!!!!!!!!!!!!
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: angelboykevin on November 12, 2009, 12:58:38 pm
lol chem doesn't deserve a board

Coz chems super fkn boring


lol   totally agree!!!
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: lukeperry91 on November 12, 2009, 12:58:47 pm
wtb chem board
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: herzy on November 12, 2009, 01:13:28 pm
hmmm i found it ok personally, i think the state will still have found it challenging... a few tricky questions were scattered in it
anyone have a copy of the blank one, or of solutions?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Cheeseball on November 12, 2009, 01:17:30 pm
I got ADCADDABB(D)DDAAACABDD

The one in brackets is question 10.  I check with a friend who also wrote his answers on the data book and we had different answers for q10 but I can't remember what he had.  The rest were the same
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: /0 on November 12, 2009, 01:18:42 pm
I think it was quite accessible and a LOT shorter than unit 3

My multiple choice:
ADCADDABBBDCAAACABDD
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: johnbpj on November 12, 2009, 01:22:06 pm
i reckon that the exam was surprisingly easy compared to mid year and last year. thought the questions were of good quality and would have tested people. I'm aiming for a A+, so hope i get it. these are my multichoice answers, let me know if you agree or disagree.
1A, 2D, 3C, 4A, 5C, 6D, 7A, 8D, 9B, 10D, 11D, 12D, 13D, 14A, 15A, 16D, 17A, 18B, 19D, 20D
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: gil.fish on November 12, 2009, 01:22:58 pm
Does anyone have the exam solutions? 8-)
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: TheJosh on November 12, 2009, 01:26:49 pm
Does anyone have the exam solutions? 8-)

*Looks for TT and waits* 8-)
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: phuiii on November 12, 2009, 01:46:56 pm
That exam was much easier than I expected, considering the midyear was torture.
Didn't manage to finish the battery question, but got everything else done.
OMG how good was the "unchanged" with the 6 boxes=6 marks OMG so easy.
And the production of the chemical.

Gah the Biofuel one kinda threw me off though
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: TheJosh on November 12, 2009, 01:48:00 pm
what would be a raw material of bioethanol
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: /0 on November 12, 2009, 01:50:12 pm
I put glucose (raw material) goes to ethanol

(equation is
  )
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: mystikal on November 12, 2009, 01:51:01 pm
NOOO i put YEAST CRAP ==!!!
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Over9000 on November 12, 2009, 01:52:40 pm
Chem is as shit as the sun is hot.
Wait, maybe thats an understatement.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Cheeseball on November 12, 2009, 01:53:29 pm
I also said ethanol for my biofuel.
I just said sugar cane, which it essentially glucose anyway but I don't think an equation was necessary.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: mystikal on November 12, 2009, 01:55:21 pm
nooooo == dam YYY!! me == stupid yeast
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: TrueTears on November 12, 2009, 02:00:20 pm
Does anyone have the exam solutions? 8-)

*Looks for TT and waits* 8-)
LOL not for chem! I'm not confident with chem :(
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: dylanru on November 12, 2009, 02:01:18 pm
I also said ethanol for my biofuel.
I just said sugar cane, which it essentially glucose anyway
same here
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: TheJosh on November 12, 2009, 02:01:38 pm
Does anyone have the exam solutions? 8-)

*Looks for TT and waits* 8-)

LOL not for chem! I'm not confident with chem :(

i guess youll only get 50 then...
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: TheJosh on November 12, 2009, 02:02:17 pm
what if you said glucose from plants?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: dylanru on November 12, 2009, 02:03:56 pm
Is there anywhere that will post the chemistry solutions? Like itute for maths and physics, but for chem?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: homghomg1 on November 12, 2009, 02:05:46 pm
That exam was much easier than I expected, considering the midyear was torture.
Didn't manage to finish the battery question, but got everything else done.
OMG how good was the "unchanged" with the 6 boxes=6 marks OMG so easy.
And the production of the chemical.

Gah the Biofuel one kinda threw me off though
I got lower, higher higher for first row
and higher higher unchanged for second row
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: /0 on November 12, 2009, 02:06:13 pm
That exam was much easier than I expected, considering the midyear was torture.
Didn't manage to finish the battery question, but got everything else done.
OMG how good was the "unchanged" with the 6 boxes=6 marks OMG so easy.
And the production of the chemical.

Gah the Biofuel one kinda threw me off though
I got lower, higher higher for first row
and higher higher unchanged for second row

high five!
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: rajah21 on November 12, 2009, 02:08:46 pm
That exam was much easier than I expected, considering the midyear was torture.
Didn't manage to finish the battery question, but got everything else done.
OMG how good was the "unchanged" with the 6 boxes=6 marks OMG so easy.
And the production of the chemical.

Gah the Biofuel one kinda threw me off though
I got lower, higher higher for first row
and higher higher unchanged for second row

high five!
+1 :D
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: /0 on November 12, 2009, 02:10:50 pm
Did anyone get a copy of the exam? I tried to get one off the examiner but he was having none of it
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: TrueTears on November 12, 2009, 02:11:49 pm
Did anyone get a copy of the exam? I tried to get one off the examiner but he was having none of it
I tried, but the examiners for physics and chem are gay ass, won't let me get a copy ffs.

They were much nicer for spesh and methods.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Over9000 on November 12, 2009, 02:13:16 pm
Did anyone get a copy of the exam? I tried to get one off the examiner but he was having none of it
He sed get it from a chem teacher, didnt you go and get it?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: /0 on November 12, 2009, 02:14:03 pm
Did anyone get a copy of the exam? I tried to get one off the examiner but he was having none of it
He sed get it from a chem teacher, didnt you go and get it?

nah couldn't find my chem teacher
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: homghomg1 on November 12, 2009, 02:14:51 pm
I think it was quite accessible and a LOT shorter than unit 3

My multiple choice:
ADCADDABBBDCAAACABDD

yeah i got the same as you :)
except for the last question OMG
easiest MC, the one about the electrolysis of lithium, i think i wrote down the wrong letter on my answer sheet by accident
either that, or i copied it onto my data booklet incorrectly
im hoping the latter...
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Over9000 on November 12, 2009, 02:14:56 pm
Did anyone get a copy of the exam? I tried to get one off the examiner but he was having none of it
He sed get it from a chem teacher, didnt you go and get it?

nah couldn't find my chem teacher
That damn JJJJJJJJJJJJJ
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: tommyk221 on November 12, 2009, 02:17:54 pm
I think it was quite accessible and a LOT shorter than unit 3

My multiple choice:
ADCADDABBBDCAAACABDD

yeah i got the same as you :)
except for the last question OMG
easiest MC, the one about the electrolysis of lithium, i think i wrote down the wrong letter on my answer sheet by accident
either that, or i copied it onto my data booklet incorrectly
im hoping the latter...

Yeah same MC. Goooood :)
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: NE2000 on November 12, 2009, 02:22:00 pm
Can anyone post the paper, if not the solutions?

It was easier than midyears, but this stresses me out as silly mistakes count more. Took it pretty slow though to avoid them first time around.

For the one where it's like, write an overall equation to show why not to use iron, did ppl just write iron reacting with the
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: avram_grant on November 12, 2009, 02:23:34 pm
Can anyone post the paper, if not the solutions?

It was easier than midyears, but this stresses me out as silly mistakes count more. Took it pretty slow though to avoid them first time around.

For the one where it's like, write an overall equation to show why not to use iron, did ppl just write iron reacting with the

Yeh, i wrote the equation for it and said iron would be preferentially oxidise since lower e0 value
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: avram_grant on November 12, 2009, 02:24:28 pm
what did you guys get for the last q?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Cheeseball on November 12, 2009, 02:24:54 pm
For the one where it's like, write an overall equation to show why not to use iron, did ppl just write iron reacting with the

I wrote the equation of Iron being oxidised with the E0 value to show it is a stronger reductant and hence will react in preference
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: avram_grant on November 12, 2009, 02:25:44 pm
lead? lol
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: homghomg1 on November 12, 2009, 02:26:42 pm
Can anyone post the paper, if not the solutions?

It was easier than midyears, but this stresses me out as silly mistakes count more. Took it pretty slow though to avoid them first time around.

For the one where it's like, write an overall equation to show why not to use iron, did ppl just write iron reacting with the
hmm, it said iron as the B electrode if i recall correctly
which means   / cell
So i wrote an overall reaction of iron reacting with (iron was lower on the electrochemical series, so it would act as a reductant, which means it would reduce the )

Title: Re: Chemistry Unit 4 Exam Discussion
Post by: argentum on November 12, 2009, 02:27:18 pm
I have scanned the paper and am uploading it now =]
For some reason it has to be verified, so wont be a minute guys!
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: avram_grant on November 12, 2009, 02:28:06 pm
Can anyone post the paper, if not the solutions?

It was easier than midyears, but this stresses me out as silly mistakes count more. Took it pretty slow though to avoid them first time around.

For the one where it's like, write an overall equation to show why not to use iron, did ppl just write iron reacting with the
hmm, it said iron as the B electrode if i recall correctly
which means   / cell
So i wrote an overall reaction of iron reacting with (iron was lower on the electrochemical series, so it would act as a reductant, which means it would reduce the )



I think you had to combien iron with the VO2+ equation since VO2+ would be reduced
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Ilovemathsmeth on November 12, 2009, 02:28:06 pm
Thanks HEAPS =D
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: /0 on November 12, 2009, 02:28:20 pm
oh yeah i wrote too but I can't remember why I chose it over the other one

If it said electrode B then .. shit i need the exam paper can't remember
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: homghomg1 on November 12, 2009, 02:28:24 pm
wait, i can't remember now, maybe it said electrode A
in which case you'd be correct
hope i didn't misread
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: simpak on November 12, 2009, 02:28:36 pm
Can anyone post the paper, if not the solutions?

It was easier than midyears, but this stresses me out as silly mistakes count more. Took it pretty slow though to avoid them first time around.

For the one where it's like, write an overall equation to show why not to use iron, did ppl just write iron reacting with the
hmm, it said iron as the B electrode if i recall correctly
which means   / cell
So i wrote an overall reaction of iron reacting with (iron was lower on the electrochemical series, so it would act as a reductant, which means it would reduce the )



+1
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: rajah21 on November 12, 2009, 02:29:18 pm
what did you guys get for the last q?

From memory, something like 1.48 A? Not sure if that's correct, though.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: TheJosh on November 12, 2009, 02:29:30 pm
what did you guys get for the last q?

1.4something Amps ^^ yeah 1.48A
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: argentum on November 12, 2009, 02:29:50 pm
http://www.mediafire.com/?md0gzqmm2kl
Enjoy guys =D, I admit its a lil crappy though
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: methodsboy on November 12, 2009, 02:29:56 pm
umm for the biofuel..I put biodesial. is that still correcT?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: methodsboy on November 12, 2009, 02:30:25 pm
what did you guys get for the last q?

1.4something Amps ^^ yeah 1.48A
got 1.47 A --> same thing anyway
did anyone get 21.0kJ for the calorimeter?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: dylanru on November 12, 2009, 02:30:38 pm
wait, i can't remember now, maybe it said electrode A
in which case you'd be correct
hope i didn't misread
It said negative electrode or something like that

[EDIT] - electrode B
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: tommyk221 on November 12, 2009, 02:34:23 pm
umm for the biofuel..I put biodesial. is that still correcT?

Yep
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: TheJosh on November 12, 2009, 02:34:41 pm
what did you guys get for the last q?

1.4something Amps ^^ yeah 1.48A
got 1.47 A --> same thing anyway
did anyone get 21.0kJ for the calorimeter?

i did
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: homghomg1 on November 12, 2009, 02:35:55 pm
just checked it said electrode B
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: /0 on November 12, 2009, 02:36:04 pm
Yeah looks like electrode B is
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Ilovemathsmeth on November 12, 2009, 02:36:37 pm
I said biodiesel too! I'm not sure what the raw material is though :( Would methanol be incorrect?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: methodsboy on November 12, 2009, 02:37:50 pm
I said biodiesel too! I'm not sure what the raw material is though :( Would methanol be incorrect?
OMG I said methanol as well!!!!!!!!!!!!!
ur prob right since u go to MGGS
From unit 3 : biodesial : fatty acid + methanol yeah?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: rajah21 on November 12, 2009, 02:38:09 pm
What was the reason for the reaction between H2 and Cu2+ not occuring?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: /0 on November 12, 2009, 02:38:38 pm
What was the reason for the reaction between H2 and Cu2+ not occuring?

The electrochemical series only predicts if reactions happen, it doesn't predict the rate at which they happen. It was probably a very slow reaction
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: methodsboy on November 12, 2009, 02:38:50 pm
What was the reason for the reaction between H2 and Cu2+ not occuring?
i said conditions were diff to standard conditions
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: simpak on November 12, 2009, 02:39:04 pm
umm for the biofuel..I put biodesial. is that still correcT?

Yep

But, the one they gave you is a biodiesel.
I had biodiesel and then I changed it at the last minute because the thing they gave you was oneeeeeee.
So unsure if it'll be accepted.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: simpak on November 12, 2009, 02:39:42 pm
What was the reason for the reaction between H2 and Cu2+ not occuring?
i said conditions were diff to standard conditions

I said reaction rate occurred too slowly for it to be observed.
It's either what is above, that, or the activation energy was not met.
Those were your options.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: NE2000 on November 12, 2009, 02:41:38 pm
Argh...yeah electrode B. The way I was thinking was that iron would react instead of V2+ or whatever so I gave the equation of it reacting preferentially. Didn't think about the fact that the real problem is it reacts with something in the compartment itself! omg silly errors

I think biodiesel would be ok, they said other than methyl palmitate, they didn't want you to just write methyl palmitate, although I should've thought about that before writing it. omg fail.



Title: Re: Chemistry Unit 4 Exam Discussion
Post by: simpak on November 12, 2009, 02:42:59 pm
Argh...yeah electrode B. The way I was thinking was that iron would react instead of V2+ or whatever so I gave the equation of it reacting preferentially. Didn't think about the fact that the real problem is it reacts with something in the compartment itself! omg silly errors

I think biodiesel would be ok, they said other than methyl palmitate, they didn't want you to just write methyl palmitate, although I should've thought about that before writing it. omg fail.





Yeah I think that this is true, because I think a lot of people would have chosen biodiesel.
But the reason I realised, was that I thought maybe, they wanted me to use a specific chemical.
So I went to the data book to find a raw material fatty acid.
And I was like "OMG THAT'S THE ONE THEY'VE GIVEN US, CHANGE TO ETHANOL NOW!"
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: TrueTears on November 12, 2009, 02:43:51 pm
Cool exam.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: NE2000 on November 12, 2009, 02:44:42 pm
Argh...yeah electrode B. The way I was thinking was that iron would react instead of V2+ or whatever so I gave the equation of it reacting preferentially. Didn't think about the fact that the real problem is it reacts with something in the compartment itself! omg silly errors

I think biodiesel would be ok, they said other than methyl palmitate, they didn't want you to just write methyl palmitate, although I should've thought about that before writing it. omg fail.





Yeah I think that this is true, because I think a lot of people would have chosen biodiesel.
But the reason I realised, was that I thought maybe, they wanted me to use a specific chemical.
So I went to the data book to find a raw material fatty acid.
And I was like "OMG THAT'S THE ONE THEY'VE GIVEN US, CHANGE TO ETHANOL NOW!"

Anyway the thing about using up food stocks still applies (as they get the fatty acids off plant materials)
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: /0 on November 12, 2009, 02:44:49 pm
Cool exam.

(http://s3-llnw-screenshots.wegame.com/5-0663891325055718/0663891325055718_l.png)
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: NE2000 on November 12, 2009, 02:45:37 pm
Oh yeah, are there any restrictions in terms of what hydrogen peroxide reacts with (apart from the normal electrochemical series stuff). I would've reacted it with itself as that is the most commonly cited one but decided to pick one where it only reacts as a reductant.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: homghomg1 on November 12, 2009, 02:46:54 pm
some of my answers which i wrote down:
Q2) c) iii) mass of NH4NO3 = 3.6 g
Q3) c) ii) 0.815 mol of dimethyl blah blah iii) 1.97 mol of methanol originally
Q4) a) 3.39 kJ/C b) 21.0 kJ c) energy released is 1.07 * 10^4 kJ/mol of methyl palmitate d) - 2.14 * 10^4 kJ/mol (of reaction)
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: /0 on November 12, 2009, 02:48:22 pm
some of my answers which i wrote down:
Q2) c) iii) mass of NH4NO3 = 3.6 g
Q3) c) ii) 0.815 mol of dimethyl blah blah iii) 1.97 mol of methanol originally
Q4) a) 3.39 kJ/C b) 21.0 kJ c) energy released is 1.07 * 10^4 kJ/mol of methyl palmitate d) - 2.14 * 10^4 kJ/mol (of reaction)

agreed except perhaps you meant 0.815M methanol in q3 c) :P
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: NE2000 on November 12, 2009, 02:50:01 pm
some of my answers which i wrote down:
Q2) c) iii) mass of NH4NO3 = 3.6 g
Q3) c) ii) 0.815 mol of dimethyl blah blah iii) 1.97 mol of methanol originally
Q4) a) 3.39 kJ/C b) 21.0 kJ c) energy released is 1.07 * 10^4 kJ/mol of methyl palmitate d) - 2.14 * 10^4 kJ/mol (of reaction)

agreed except perhaps you meant 0.815M methanol in q3 c) :P

Agreed with those as well
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: NE2000 on November 12, 2009, 02:54:21 pm
OK so electrode A was positive, B negative? had highest concentration after being fully charged (not sure but they meant the anode during charging right? As in electrode A). so for the equation you are adding the bottom left and top right.

for the way in which they differ I think I put something about fuel cells generally not made to electrolyze the reactants ala a secondary galvanic cells. Continuous flow of reactants was an option but something about the pump turned me away from that.

Recycle the heat energy to reaction 1
And the oxidation reaction was that of water going to O2, 4H+ etc?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: TrueTears on November 12, 2009, 02:55:00 pm
Funny I can't remember anything from that exam =S
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: NE2000 on November 12, 2009, 02:55:55 pm
Funny I can't remember anything from that exam =S

I couldn't until I saw the exam again lol. I think I went into relax mode a couple of hours too early, creating my own problems with silly mistakes
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: TheJosh on November 12, 2009, 02:56:50 pm


for the way in which they differ I think I put something about fuel cells generally not made to electrolyze the reactants ala a secondary galvanic cells. Continuous flow of reactants was an option but something about the pump turned me away from that.


i said you cant recharge fuel cells they just require continuous supply of reactant in order to maintain electricity production
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Ilovemathsmeth on November 12, 2009, 03:06:10 pm
Damn, MC was trickier than I thought =(
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: ScyLLa on November 12, 2009, 03:10:43 pm
I also said ethanol for my biofuel.
I just said sugar cane, which it essentially glucose anyway but I don't think an equation was necessary.

OMFG..... i cant believe it. i put that answer thinking why i even bother doing chem. LOL

it was honestly the most random thing that came to my head. 
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: TheJosh on November 12, 2009, 03:12:15 pm
I also said ethanol for my biofuel.
I just said sugar cane, which it essentially glucose anyway but I don't think an equation was necessary.

OMFG..... i cant believe it. i put that answer thinking why i even bother doing chem. LOL

it was honestly the most random thing that came to my head. 


The Chem gods bestowed their knowledge unto you  :angel:
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: btuned on November 12, 2009, 03:14:59 pm
some of my answers which i wrote down:
Q2) c) iii) mass of NH4NO3 = 3.6 g
Q3) c) ii) 0.815 mol of dimethyl blah blah iii) 1.97 mol of methanol originally
Q4) a) 3.39 kJ/C b) 21.0 kJ c) energy released is 1.07 * 10^4 kJ/mol of methyl palmitate d) - 2.14 * 10^4 kJ/mol (of reaction)

Same here! I was thinking the values of H were too alrge to be a combustion of a biodiesel. But then again.. it's an exam after all, bullshit values might sometimes be the right one
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: /0 on November 12, 2009, 03:20:14 pm
What would be a HAZCHEM symbol for sulfuric acid?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: ron09 on November 12, 2009, 03:21:10 pm
for MC i got 1)ACCADDABBB 11)DCAAACABBD

for short answer... i got these
1)a H202 + 2Ag+ -> O2 + 2H+ + 2Ag (I used Ag as an example to make and overall eqn to demonstrate H2O2 acting as reductant)
1)b I wasn't sure..i said no electrodes so Cu can't form solid.. not sure though.

2)a ii Start at 60, go up to 120 and then down to 85
2)b i NH4+ + H20 <-/-> NH3 + H3O+
2)b ii Diluted, Fwd reaction is favoured
2)b iii Equal to
2)c i Ka= ([NH3][H3O+])/([NH4+])
2)c ii 9.12x10^-6 M
2)c iii 3.56g

3)a K=([H2O][CH3OCH3])/([CH3OH]^2)
3)b K=0.174
3)c i 0.017 mol/L
3)c ii 0.815 mol
3)c iii 1.969 mol

4)a CF=3385 J/C
4)b 20.955kJ
4)c 10695KJ
4)d H=-21390 kJ/mol
4)e I chose ethanol from the anaerobic decomposition of biomass; disadvantage is that it produces CO2 (greenhouse gas)
4)f High efficiency; Harmful nuclear waste produced

5)a A=+ B=-
5)b VO2
5)c VO + H2O + V -> VO2 + 2H + V
5)d Fuel cells typically have electrodes that act as catalysts; this cell doesn't.
5)e Iron is oxidised preferentially over vanadium.

6)a LHH, UHU
6)b Heat can be used to drive reaction 1 (its endothermic)
6)c Chose Sulfuric Acid; i Reuse excess H2SO4 to create Oleum (not sure whether this will suffice! but couldn't think of anything else) ii Corrosive; iii Dehydrating agent and used in production of fertilizers (super phosphate).

7)a SO4^2- -> SO4 + 2e- (not sure)
7)b 1.48A

Not fully sure on the correctness of everything..but I found the exam fairly straightfwd.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: homghomg1 on November 12, 2009, 03:30:37 pm
for MC i got 1)ACCADDABBB 11)DCAAACABBD

for short answer... i got these
1)a H202 + 2Ag+ -> O2 + 2H+ + 2Ag (I used Ag as an example to make and overall eqn to demonstrate H2O2 acting as reductant)
1)b I wasn't sure..i said no electrodes so Cu can't form solid.. not sure though.

2)a ii Start at 60, go up to 120 and then down to 85
2)b i NH4+ + H20 <-/-> NH3 + H3O+
2)b ii Diluted, Fwd reaction is favoured
2)b iii Equal to
2)c i Ka= ([NH3][H3O+])/([NH4+])
2)c ii 9.12x10^-6 M
2)c iii 3.56g

3)a K=([H2O][CH3OCH3])/([CH3OH]^2)
3)b K=0.174
3)c i 0.017 mol/L
3)c ii 0.815 mol
3)c iii 1.969 mol

4)a CF=3385 J/C
4)b 20.955kJ
4)c 10695KJ
4)d H=-21390 kJ/mol
4)e I chose ethanol from the anaerobic decomposition of biomass; disadvantage is that it produces CO2 (greenhouse gas)
4)f High efficiency; Harmful nuclear waste produced

5)a A=+ B=-
5)b VO2
5)c VO + H2O + V -> VO2 + 2H + V
5)d Fuel cells typically have electrodes that act as catalysts; this cell doesn't.
5)e Iron is oxidised preferentially over vanadium.

6)a LHH, UHU
6)b Heat can be used to drive reaction 1 (its endothermic)
6)c Chose Sulfuric Acid; i Reuse excess H2SO4 to create Oleum (not sure whether this will suffice! but couldn't think of anything else) ii Corrosive; iii Dehydrating agent and used in production of fertilizers (super phosphate).

7)a SO4^2- -> SO4 + 2e- (not sure)
7)b 1.48A

Not fully sure on the correctness of everything..but I found the exam fairly straightfwd.

2 b) ii) was removal of products. if it was dilution, the rate of backward and foward reaction would have suddenly dropped for both. this was only seen for backwards rate though, which indicates products have been removed (lower concentration of products = less collisions = lower backwards rate)

since there are now less products, there is a net reaction foward, and over time the rate of reaction foward GRADUALLY decreases, while the backwards rate GRADUALLY increases, as is demonstrated by the graph

for 5) d) i said that fuel cells usually have gaseous reactants, but in this cell the reactants are ions in an aqueous solution

for 1) b) i said conditions may not have been standard (25 degrees and 1.0 M concentration of Cu2+), as is required for predictions made by electrochemical series to be correct
but i think the safer answer is to say the electrochemical series does not predict rate of reaction; hence there may have been a very slow rate
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Cheeseball on November 12, 2009, 03:30:51 pm
for MC i got 1)ADCADDABBB 11)DCAAACABDD

for short answer... i got these
1)a H202 + 2Ag+ -> O2 + 2H+ + 2Ag (I used Ag as an example to make and overall eqn to demonstrate H2O2 acting as reductant)
1)b Rate is too slow

2)a ii Start at 60, go up to 120 and then down to 85
2)b i NH4+ + H20 <-/-> NH3 + H3O+
2)b ii Removal of products
2)b iii Equal to
2)c i Ka= ([NH3][H3O+])/([NH4+])
2)c ii 9.12x10^-6 M
2)c iii 3.56g

3)a K=([H2O][CH3OCH3])/([CH3OH]^2)
3)b K=0.174
3)c i 0.017 mol/L
3)c ii 0.815 mol
3)c iii 1.969 mol

4)a CF=3385 J/C
4)b 20.955kJ
4)c 10695KJ
4)d H=-21390 kJ/mol
4)e I chose ethanol from the anaerobic decomposition of biomass; disadvantage is that it produces CO2 (greenhouse gas)
4)f High efficiency; Harmful nuclear waste produced

5)a A=+ B=-
5)b VO2
5)c VO + H2O + V -> VO2 + 2H + V
5)d Fuel cells typically have electrodes that act as catalysts; this cell doesn't.
5)e Iron is oxidised preferentially over vanadium.

6)a LHH, HHU
6)b Heat can be used to drive reaction 1 (its endothermic)
6)c Chose Sulfuric Acid; reuse unreacted reactants (its equilibrium so there will be some) ii Corrosive; iii Dehydrating agent and used in production of fertilizers (super phosphate).

7)a some h2o reaction (not sure)
7)b 1.48A

Not fully sure on the correctness of everything..but I found the exam fairly straightfwd.

bolded text are changes
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Ilovemathsmeth on November 12, 2009, 03:39:03 pm
For that 'removal of products' one, could you have said addition of products?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: ron09 on November 12, 2009, 03:40:36 pm
Thanks :) I feel good now that I didn't get that many wrong! lol
7)a was tricky..didnt think of water; 6)c again didn't think of it! lol; 2b ii Another oversight
with around 8 marks in total gone.. is it still possible for an A+?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: /0 on November 12, 2009, 03:42:27 pm
For that 'removal of products' one, could you have said addition of products?

the forward and backward rates of the second equilibrium are lower than the first, so there must be less collisions and hence less particles overall :/
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: simpak on November 12, 2009, 03:46:00 pm
Yeah it's not addition of products.
I think I lost an answer mark because my calc is shit, and for the Electrode B question (because I don't have time to download the pdf rn...)
Did it ask you to EXPLAIN why Fe couldn't be used as well as the half eq?  Because if so I missed that bit, crap.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: d0minicz on November 12, 2009, 03:47:00 pm
Thanks :) I feel good now that I didn't get that many wrong! lol
7)a was tricky..didnt think of water; 6)c again didn't think of it! lol; 2b ii Another oversight
with around 8 marks in total gone.. is it still possible for an A+?

i believe so
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: /0 on November 12, 2009, 03:47:35 pm
Yeah it's not addition of products.
I think I lost an answer mark because my calc is shit, and for the Electrode B question (because I don't have time to download the pdf rn...)
Did it ask you to EXPLAIN why Fe couldn't be used as well as the half eq?  Because if so I missed that bit, crap.

nope, 1 mark 1 equation :)
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: homghomg1 on November 12, 2009, 03:48:54 pm
Yeah it's not addition of products.
I think I lost an answer mark because my calc is shit, and for the Electrode B question (because I don't have time to download the pdf rn...)
Did it ask you to EXPLAIN why Fe couldn't be used as well as the half eq?  Because if so I missed that bit, crap.
It's a 1 mark question and it asks to write an equation which shows why iron isn't suitable, so you didn't have to explain in words i think
i wrote a short sentence just in case
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: ron09 on November 12, 2009, 03:49:20 pm
Umm its not the half eqn they are looking for. You need to include the overall eqn demonstrating its reaction with vanadium :)
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Cheeseball on November 12, 2009, 03:49:56 pm
"Write a balanced overall equation to show why iron would be an unsuitable material to use as electrode B in the vanadium redox cell."

It's only worth one mark and I got it wrong :(  I wrote the iron oxidation half equation
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: kendraaaaa on November 12, 2009, 03:52:29 pm
So happy. Everything is looking good but I know I stuffed up the 'calculate the mass of NH3OH" or whatever question, I got like 0.0035 or something. But apart from that it's all good.

Any else found that the MC took them longer than 20 minutes? Took me like 25 to almost 30. I got kind of panicky then! Haha
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: tommyk221 on November 12, 2009, 03:56:39 pm
So happy. Everything is looking good but I know I stuffed up the 'calculate the mass of NH3OH" or whatever question, I got like 0.0035 or something. But apart from that it's all good.

Any else found that the MC took them longer than 20 minutes? Took me like 25 to almost 30. I got kind of panicky then! Haha

Haha same I got something really small as well. Oh well.
And yeah MC took me a while, about 25 mins.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: IntoTheNewWorld on November 12, 2009, 04:01:15 pm
So happy. Everything is looking good but I know I stuffed up the 'calculate the mass of NH3OH" or whatever question, I got like 0.0035 or something. But apart from that it's all good.

Any else found that the MC took them longer than 20 minutes? Took me like 25 to almost 30. I got kind of panicky then! Haha

Haha same I got something really small as well. Oh well.
And yeah MC took me a while, about 25 mins.

took me a while too, but I did short answer first.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Dark Horse on November 12, 2009, 04:01:32 pm
For the question what will have the highest concnetration at the anode after recharge, wouldnt it be V2+? Please tell me it is :(
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: homghomg1 on November 12, 2009, 04:05:43 pm
For the question what will have the highest concnetration at the anode after recharge, wouldnt it be V2+? Please tell me it is :(
yeah some people at my school got V2+
i thought it was veryyyy ambiguous
anode changes depending on whether it's discharging or recharging!
but in the end, it comes down to the fact that they say fully charged in bold
this means it can't be any more charged, and the only possibility is for discharge to occur, in which case electrode B is the anode, and V2+ is highest concentration
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: simpak on November 12, 2009, 04:07:44 pm
Re: One mark just equation, too many to quote.
Thanks guys, that makes me feel better!  In that case, should have only lost about two or three marks on long answer.
Still need to check MC.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: /0 on November 12, 2009, 04:08:49 pm
The question is equivalent to "As the cell recharges, which species eventually has the greatest concentration at the anode?"

If we arrange the equations so that the cell is recharging, isn't the anode electrode A?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: simpak on November 12, 2009, 04:11:50 pm
Wait what do we think it is?
I put VO with a charge of 2+
The second one.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: /0 on November 12, 2009, 04:13:49 pm
Wait what do we think it is?
I put VO with a charge of 2+
The second one.

The question is equivalent to "As the cell recharges, which species eventually has the greatest concentration at the anode?"

If we arrange the equations so that the cell is recharging, isn't the anode electrode A?

If the anode is electrode A when the cell is recharging then the equation is

And from this I got
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: kev0 on November 12, 2009, 04:15:04 pm
Quote
2)a ii Start at 60, go up to 120 and then down to 85

Do you mean.
Start at 60, Go to 70 then down to 35?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: kendraaaaa on November 12, 2009, 04:15:53 pm
Are you sure fully charged is the same as "as the cell recharges", I think this is a bit vague. Because it says in the question "when the cell is fully charged" which I interpreted that the reactant at the anode will have a higher concentration than the product. Which would be V2+

Not sure though
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Cheeseball on November 12, 2009, 04:16:10 pm
Quote
2)a ii Start at 60, go up to 120 and then down to 85

Do you mean.
Start at 60, Go to 70 then down to 35?

It was endothermic
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: kendraaaaa on November 12, 2009, 04:17:16 pm
Quote
2)a ii Start at 60, go up to 120 and then down to 85

Do you mean.
Start at 60, Go to 70 then down to 35?

It was endothermic

+1, OP is right.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: /0 on November 12, 2009, 04:18:15 pm
Are you sure fully charged is the same as "as the cell recharges", I think this is a bit vague. Because it says in the question "when the cell is fully charged" which I interpreted that the reactant at the anode will have a higher concentration than the product. Which would be V2+

Not sure though

Ah I see what you mean... yes that is very ambiguous. Either equation could occur at the anode depending on whether it is charging or not.

Do you think they'll scrap the question?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: roberem on November 12, 2009, 04:18:58 pm
What would be a HAZCHEM symbol for sulfuric acid?
corrosive :)
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: /0 on November 12, 2009, 04:19:22 pm
What would be a HAZCHEM symbol for sulfuric acid?
corrosive :)

cooool
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: homghomg1 on November 12, 2009, 04:19:40 pm
The question is equivalent to "As the cell recharges, which species eventually has the greatest concentration at the anode?"

If we arrange the equations so that the cell is recharging, isn't the anode electrode A?
yeah that's where the ambiguity comes in
could be interpreted as the anode when the cell has JUST finished recharging, or could be interpreted as the anode when the cell is discharging, since it is fully charged and can't recharge any further
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: rajah21 on November 12, 2009, 04:21:14 pm
For 2)c iii (the mass of NH4NO3), how did you get 3.56g? I think I got something way smaller but I'm not sure how :S
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: kendraaaaa on November 12, 2009, 04:23:57 pm
For 2)c iii (the mass of NH4NO3), how did you get 3.56g? I think I got something way smaller but I'm not sure how :S

I was confused with this question.

I found the concentration of NH4+ ions by using the pH value to find [H+] and used the Ka value from the booklet. Then I found the mole of NH4. Then to get the mass, do you use the molar value of NH4 or NH4NO3. Is my working correct though? Haha blargh
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: PepsiMax on November 12, 2009, 04:24:19 pm
What would be a HAZCHEM symbol for sulfuric acid?
corrosive :)
cooool
According to my chem textbook -
Toxic
Corrosive
Oxidising

I chose oxidising because I remembered that sulfuric acid is a strong oxidising agent.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: rajah21 on November 12, 2009, 04:25:47 pm
For 2)c iii (the mass of NH4NO3), how did you get 3.56g? I think I got something way smaller but I'm not sure how :S

I was confused with this question.

I found the concentration of NH4+ ions by using the pH value to find [H+] and used the Ka value from the booklet. Then I found the mole of NH4. Then to get the mass, do you use the molar value of NH4 or NH4NO3. Is my working correct though? Haha blargh

Ah crap. I think I found the mass of NH4+ because I used the same method as you but I didn't find the n(NH4NO3) in order to find the mass. Damn!
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Cheeseball on November 12, 2009, 04:29:34 pm
What would be a HAZCHEM symbol for sulfuric acid?
corrosive :)
cooool
According to my chem textbook -
Toxic
Corrosive
Oxidising

I chose oxidising because I remembered that sulfuric acid is a strong oxidising agent.

I chose oxidising and straight after the exam I was thinking I should've picked corrosive because it's the safe answer
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: btuned on November 12, 2009, 04:37:24 pm
Grrr just can't wait for the solutions. Where's TrueTears at? haha
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: gallinari on November 12, 2009, 04:41:16 pm
For the question saying why won't Cu2+ react with H2, do you reckon it was valid to write: because the 2H+ can also react with the SO42- in an acid base reaction, thus decreasing the amount of H2 available for redox reaction with Cu2+??
:S
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Sardi on November 12, 2009, 04:41:44 pm
do we have a majority on the mulitple choice answers yet?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: kendraaaaa on November 12, 2009, 04:43:52 pm
do we have a majority on the mulitple choice answers yet?

I used /0's answers which were on page one. I got 17/20 according to that, and the ones I got wrong were the ones I thought I would. So yeah, they seem pretty reliable.

For the question saying why won't Cu2+ react with H2, do you reckon it was valid to write: because the 2H+ can also react with the SO42- in an acid base reaction, thus decreasing the amount of H2 available for redox reaction with Cu2+??
:S

I think the safest answer would be to to say that the reaction rate may have been very slow hence no observations could be made.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Sardi on November 12, 2009, 04:46:06 pm
Can you republish them?
This board is like, 9 pages!!
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Cheeseball on November 12, 2009, 04:49:01 pm
For the question saying why won't Cu2+ react with H2, do you reckon it was valid to write: because the 2H+ can also react with the SO42- in an acid base reaction, thus decreasing the amount of H2 available for redox reaction with Cu2+??
:S

Where the hell is the 2H+ coming from?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: rajah21 on November 12, 2009, 04:49:08 pm
/0's MC answers :)

I think it was quite accessible and a LOT shorter than unit 3

My multiple choice:
ADCADDABBBDCAAACABDD
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: homghomg1 on November 12, 2009, 04:52:37 pm
i know this is annoying :D, but does anyone have any indication of what a+ sacs in a good cohort, 67/73 and 73/76 for exam 1 and 2 is capable of getting
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: PepsiMax on November 12, 2009, 04:54:12 pm
i know this is annoying :D, but does anyone have any indication of what a+ sacs in a good cohort, 67/73 and 73/76 for exam 1 and 2 is capable of getting
http://vcenotes.com/forum/index.php/topic,6688.0.html
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: btuned on November 12, 2009, 04:54:21 pm
i know this is annoying :D, but does anyone have any indication of what a+ sacs in a good cohort, 67/73 and 73/76 for exam 1 and 2 is capable of getting
46? Lmao
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Dark Horse on November 12, 2009, 04:54:45 pm
I got the same multi choice answers!
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: PepsiMax on November 12, 2009, 04:54:52 pm
Great.... there was a question that requested a suitable amount of significant figures....
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Cheeseball on November 12, 2009, 04:57:58 pm
i know this is annoying :D, but does anyone have any indication of what a+ sacs in a good cohort, 67/73 and 73/76 for exam 1 and 2 is capable of getting
46? Lmao

It's basing it off last years scores though.  Remember this years midyear exam was a killer
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: tommyk221 on November 12, 2009, 05:02:36 pm
For 2)c iii (the mass of NH4NO3), how did you get 3.56g? I think I got something way smaller but I'm not sure how :S

I got a smaller answer as well. I have no idea where I went wrong. But I certainly did go wrong haha
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: bloodboy on November 12, 2009, 05:03:05 pm
is the 1.0M solution of Cabr2 mean that br is twice as concentrated?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: tommyk221 on November 12, 2009, 05:04:56 pm
The most popular MC's are the same as /0's
ADCADDABBBDCAAACABDD
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: rhjc.1991 on November 12, 2009, 05:09:35 pm
YES!!!! GOT THE SAME AS /0!! 20/20 for MCQ for me!!
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: NE2000 on November 12, 2009, 05:10:35 pm
Yeah for the charge one I picked the one on the very left (VO2 with a +?) because I assumed fully charged means it hasn't discharged. As the reaction is spontaneous, there is only a tiny instant when the discharging reaction would be occurring and it would still be fully charged. Still ambiguous I guess.

EDIT: MAKE SOME ROOM PEOPLE COZ I'M PART OF THE FURNITURE!!!!!!!!!!!!!!!!!!!!!
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: StringFever on November 12, 2009, 05:13:12 pm
Hey guys,

Wondering what people said the "raw material" was for Biogas if you put that down as your response in the exam? :)
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: NE2000 on November 12, 2009, 05:15:05 pm
Oh and what's the view on the biodiesel then. The question clearly stated not to use the methyl ..., so did that mean no biodiesels or was it simply to ensure people don't try and secure the mark by just using the thing given in the question. 2 marks riding on that (my explanation for why it's a problem is not unique to biodiesels so I hope they accept that :S).
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: kendraaaaa on November 12, 2009, 05:15:17 pm
is the 1.0M solution of Cabr2 mean that br is twice as concentrated?

Don't think so. It just means that two Br- ions are required, but the concentration is still 1.0M which is standard conditions.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: kev0 on November 12, 2009, 05:22:29 pm
Quote
2)a ii Start at 60, go up to 120 and then down to 85

Do you mean.
Start at 60, Go to 70 then down to 35?

It was endothermic

+1, OP is right.

Oh my bad.

The PDF scans were kinda rough on the sign. I completely forgotten about the question :I
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Hooligan on November 12, 2009, 05:35:39 pm
I said biodiesel too! I'm not sure what the raw material is though :( Would methanol be incorrect?
OMG I said methanol as well!!!!!!!!!!!!!
ur prob right since u go to MGGS
From unit 3 : biodesial : fatty acid + methanol yeah?

Yes, however, the raw material for Biodiesal is vegetable oil. Not sure if you would be mark wrong though. :P
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: NE2000 on November 12, 2009, 05:38:43 pm
I said fatty acid and methanol/ethanol (you can have some ethyl esters classified as biodiesels). I think that's more accurate than vegetable oil I think, you can get biodiesel from animal fats too
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: avram_grant on November 12, 2009, 05:59:27 pm
lol dont worry about vce anymore, its ovaaaaaa
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Dark Horse on November 12, 2009, 06:46:20 pm
For the raw material used in the production of bioethanol, is it ok to have said sugarcane? Also, do you think VCAA will accept V2+ for that ambiguous circle the species in highest concentration question?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Potter on November 12, 2009, 06:50:33 pm
is the 1.0M solution of Cabr2 mean that br is twice as concentrated?

Don't think so. It just means that two Br- ions are required, but the concentration is still 1.0M which is standard conditions.

I'd say it means there is 1 mol of Ca2+ ions and 2 mol of Br- ions.
Reason being.. If you have an ionic substance and dissolve it in water it breaks into it's cation/anion.
Since the ratio is 1:2. 2 mol of Br- will be in the solution.


Title: Re: Chemistry Unit 4 Exam Discussion
Post by: furtheyboy on November 12, 2009, 06:52:30 pm
for MC Q20:

Shouldnt the answer be B. If you have a carbon electrode, then H2O would be oxidised, which would in turn produce O2, this would result in a big reaction with the Lithium metal?

Have I got this wrong?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Potter on November 12, 2009, 06:59:18 pm
for MC Q20:

Shouldnt the answer be B. If you have a carbon electrode, then H2O would be oxidised, which would in turn produce O2, this would result in a big reaction with the Lithium metal?

Have I got this wrong?

From my understanding, C electrodes are used cause they're chemically inert. Just like Pt but a cheaper alternative.
Also, if you chose B there's no H2O in the cell. Just molten LiCl
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Hissy88 on November 12, 2009, 07:08:56 pm
Quote
2)a ii Start at 60, go up to 120 and then down to 85

Do you mean.
Start at 60, Go to 70 then down to 35?

It was endothermic

+1, OP is right.

Oh my bad.

The PDF scans were kinda rough on the sign. I completely forgotten about the question :I

It doesn't go down because that means the enthalpy is -ve so energy is released, when it is really absorbed
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: kashmuq on November 12, 2009, 07:48:49 pm
haha anyone posting up solutions? :D
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: kendraaaaa on November 12, 2009, 08:16:06 pm
is the 1.0M solution of Cabr2 mean that br is twice as concentrated?

Don't think so. It just means that two Br- ions are required, but the concentration is still 1.0M which is standard conditions.

I'd say it means there is 1 mol of Ca2+ ions and 2 mol of Br- ions.
Reason being.. If you have an ionic substance and dissolve it in water it breaks into it's cation/anion.
Since the ratio is 1:2. 2 mol of Br- will be in the solution.




That's irrelevant in this context I think, the option was simply to test whether or not you know that 1.0M was one of the standard conditions.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: NE2000 on November 12, 2009, 08:38:15 pm
for MC Q20:

Shouldnt the answer be B. If you have a carbon electrode, then H2O would be oxidised, which would in turn produce O2, this would result in a big reaction with the Lithium metal?

Have I got this wrong?

Molten LiCl so no water. If you used iron, then that would be oxidized at the anode. And if allowed the Fe2+ would travel across to the cathode and be preferentially reduced. This results in electrolytic cell fail.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: methodsboy on November 12, 2009, 08:42:28 pm
^^ so the correct answer was D?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: NE2000 on November 12, 2009, 08:43:56 pm
^^ Think so
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: kendraaaaa on November 12, 2009, 08:46:39 pm
^^ so the correct answer was D?

Yah I put D. Because firstly you needed a molten electrolyte, and secondly you couldn't use iron as the electrode because a) it's more expensive than carbon and b) the products of electrolysis would undergo a vigorous spontaneous reduction as lithium is an extremely powerful reductant.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: methodsboy on November 12, 2009, 08:47:04 pm
kewl.
ok question 12. I spent two minutes on this cause i had a sudden mental blank.
postive to positive?
negative to negative?

(at first i though it was - to + and + to -; but then i thought that the power supply determines the electrode charge)
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: kendraaaaa on November 12, 2009, 08:47:57 pm
kewl.
ok question 12. I spent two minutes on this cause i had a sudden mental blank.
postive to positive?
negative to negative?

(at first i though it was - to + and + to -; but then i thought that the power supply determines the electrode charge)


Cathode's connected to the postive terminal of the powerpack. Forgot which letters were which.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: NE2000 on November 12, 2009, 08:49:03 pm
A to C. B to D. Positive to positive. Negative to negative.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: methodsboy on November 12, 2009, 08:53:09 pm
A to C. B to D. Positive to positive. Negative to negative.
OMG i got it right! i thought it was wrong when i walked out of the room. Wait, ur not joking right?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: tripz on November 12, 2009, 08:54:00 pm
What would be a HAZCHEM symbol for sulfuric acid?
corrosive :)

cooool

Oh my goodness O.O Did I even do that question?!!?1
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: NE2000 on November 12, 2009, 08:55:14 pm
A to C. B to D. Positive to positive. Negative to negative.
OMG i got it right! i thought it was wrong when i walked out of the room. Wait, ur not joking right?

The positive and negative electrodes remain exactly the same. It's just that their roles change. Think about it, during discharge at the negative electrode (anode), oxidation occurs. You need reduction to occur during charging. Where does that occur? At the negative electrode.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: simpak on November 12, 2009, 09:06:46 pm
GUISE, WHAT HAVE WE DECIDED FOR THE AMBIGUOUS CATHODE ANODE QUESTION WITH THE VO SPECIES ETC?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Cheeseball on November 12, 2009, 09:08:25 pm
GUISE, WHAT HAVE WE DECIDED FOR THE AMBIGUOUS CATHODE ANODE QUESTION WITH THE VO SPECIES ETC?

That is it ambiguous lol.  VCAA will end up giving both answers as correct
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: angelboykevin on November 12, 2009, 09:18:10 pm
is itute solution up yet?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Cheeseball on November 12, 2009, 09:27:54 pm
itute doesn't do chem
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: phuiii on November 12, 2009, 10:46:08 pm
Wait for Mao to put up solutions.
Godly solutions on the way if Mao does rofl
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: /0 on November 13, 2009, 01:34:05 pm
I emailed my chem teacher (who is an assessor), he said fully charged means it's about to discharge.

Oh well, I don't fully agree, but what can you do about it?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: kendraaaaa on November 13, 2009, 02:39:33 pm
I emailed my chem teacher (who is an assessor), he said fully charged means it's about to discharge.

Oh well, I don't fully agree, but what can you do about it?

They'll make both of them right solutions, the question was way to ambiguous and I was lucky that I interpreted as it being 'about to discharge'.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: TheJosh on November 13, 2009, 02:44:11 pm
Hopefully /0 s answers for mc are right cause then i wouldve  got 20/20 :D :D :D
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: kendraaaaa on November 13, 2009, 04:16:05 pm
where are the answers?

First or second page of this thread. They're not 'set' answers just suggested solutions, so don't take them as gospel.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: tomygun_123 on November 13, 2009, 09:43:57 pm
i reckon that the exam was surprisingly easy compared to mid year and last year. thought the questions were of good quality and would have tested people. I'm aiming for a A+, so hope i get it. these are my multichoice answers, let me know if you agree or disagree.
1A, 2D, 3C, 4A, 5C, 6D, 7A, 8D, 9B, 10D, 11D, 12D, 13D, 14A, 15A, 16D, 17A, 18B, 19D, 20D

Wow A+... i wish i could get one too, can you teach me how, faggot.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: sir0004 on November 13, 2009, 10:59:30 pm
For question 13, i also got D but everyone else said it was A?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: simpak on November 13, 2009, 11:39:46 pm
13 I got A.  What question was that again?
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: kendraaaaa on November 13, 2009, 11:45:05 pm
13 I got A.  What question was that again?

A for me too.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: NE2000 on November 14, 2009, 07:47:48 am
I emailed my chem teacher (who is an assessor), he said fully charged means it's about to discharge.

Oh well, I don't fully agree, but what can you do about it?

Is this his view or what the markers are marking?

I hope they give both.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: simpak on November 14, 2009, 08:33:08 am
13 I got A.  What question was that again?

A for me too.

I looked it up, it's the one about the pipes.
It can't be the reduction of oxygen and water to OH guys.
Look where region X is.
It's surrounded by the water droplet; no oxygen gets through, there are only water molecules.
So it has to be the anode, because if it were the cathode, reduction would occur and it would corrode.
Only iron can react because no O2 is present to react.
The answer is A.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: coonoo on November 14, 2009, 09:10:49 am
For question 12, was the answer C or D? Its the question about the arrangement of a cell recharging. C is a A connected to C (both positive)and B  connected to D (both negative). D is A to D and B to C.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: shonira on November 14, 2009, 09:21:42 am
For question 12, was the answer C or D? Its the question about the arrangement of a cell recharging. C is a A connected to C (both positive)and B  connected to D (both negative). D is A to D and B to C.

i think the answer was C (positive-positive and negative-negative)....thats what i found from my chem textbook.....i stuffed up that question cos i initially wrote C then changed it to D at the last minute cos i was doubting myself. GRRR :I
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: simpak on November 14, 2009, 09:24:07 am
N...it's D.
The picture of the positive and negative one was the cell discharging, when the anode is negative and the cathode is positive.
Recharging is equivalent to electrolysis, therefore you have to switch them so that the anode is positive and the cathode is negative.
D.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: silva on November 14, 2009, 10:22:57 am
N...it's D.
The picture of the positive and negative one was the cell discharging, when the anode is negative and the cathode is positive.
Recharging is equivalent to electrolysis, therefore you have to switch them so that the anode is positive and the cathode is negative.
D.
ohhhhhhhhhhh you serious? thank fuck i picked D then, what you're saying sounds like the proper reasoning unless someone who picked C (negative-negative, positive-positive) could post their reasoning
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: shonira on November 14, 2009, 10:25:02 am
N...it's D.
The picture of the positive and negative one was the cell discharging, when the anode is negative and the cathode is positive.
Recharging is equivalent to electrolysis, therefore you have to switch them so that the anode is positive and the cathode is negative.
D.
ohhhhhhhhhhh you serious? thank fuck i picked D then, what you're saying sounds like the proper reasoning unless someone who picked C (negative-negative, positive-positive) could post their reasoning

omg yea i understand now....thank god i changed it to D
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: furtheyboy on November 14, 2009, 10:27:22 am
For C:
--Originally you will be having reduction occuring at the positive electrode.
--Therefore, when recharging you want those ions that have been reduced to be oxidised at the anode.
--Now, when recharging the anode is positively charged and we know that the external energy source is the decider of the polarities.
--Hence, you must attach the positive from the external source to the battery as to keep that electrode positively charged and for oxidation to occur, resulting in the corrosion of the products.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: simpak on November 14, 2009, 12:02:04 pm
For C:
--Originally you will be having reduction occuring at the positive electrode.
--Therefore, when recharging you want those ions that have been reduced to be oxidised at the anode.
--Now, when recharging the anode is positively charged and we know that the external energy source is the decider of the polarities.
--Hence, you must attach the positive from the external source to the battery as to keep that electrode positively charged and for oxidation to occur, resulting in the corrosion of the products.

Yeah on second thought that does sound relatively correct...
Wait...
Let me think for a second...
But.
Nup that's right!  SORRY GUYS, LISTEN TO THIS PERSON NOT ME.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: forsaken231 on November 14, 2009, 12:12:22 pm
yeah it's C.. although i still think 13 is A
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: kendraaaaa on November 14, 2009, 12:33:12 pm
yeah it's C.. although i still think 13 is A

It is dude
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: NE2000 on November 14, 2009, 01:22:39 pm
13 I got A.  What question was that again?

A for me too.

I looked it up, it's the one about the pipes.
It can't be the reduction of oxygen and water to OH guys.
Look where region X is.
It's surrounded by the water droplet; no oxygen gets through, there are only water molecules.
So it has to be the anode, because if it were the cathode, reduction would occur and it would corrode.
Only iron can react because no O2 is present to react.
The answer is A.

agree with this. That was my logic in the exam :)
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: elbitar on November 14, 2009, 03:54:28 pm
I got C for 13 although it was difficult to identify whether region X was related to the iron or the water but i eventually got it
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: simpak on November 14, 2009, 06:45:29 pm
Nah 13 is totally A.
Despite me being inept at the other question TRUST ME ON THIS ONE.
REGION X HAD NO AIR, NO O2.
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: PepsiMax on November 14, 2009, 07:47:49 pm
I had A for question 13 as well. I was very confident with that question as absolutely no O2 was in contact with the iron region.

I also had C for 12 as well (positive - positive, negative-negative).
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Ghost on November 15, 2009, 12:08:39 pm
13 I got A.  What question was that again?

A for me too.

I looked it up, it's the one about the pipes.
It can't be the reduction of oxygen and water to OH guys.
Look where region X is.
It's surrounded by the water droplet; no oxygen gets through, there are only water molecules.
So it has to be the anode, because if it were the cathode, reduction would occur and it would corrode.
Only iron can react because no O2 is present to react.
The answer is A.

agree with this. That was my logic in the exam :)

This was also my logic in the exam.. At region X oxidation would occur, providing electrons for the reduction reaction which would occur in the presence of Oxygen gas, at region Y.. That whats i was thinking
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: shonira on November 15, 2009, 01:52:08 pm
13 I got A.  What question was that again?

A for me too.

I looked it up, it's the one about the pipes.
It can't be the reduction of oxygen and water to OH guys.
Look where region X is.
It's surrounded by the water droplet; no oxygen gets through, there are only water molecules.
So it has to be the anode, because if it were the cathode, reduction would occur and it would corrode.
Only iron can react because no O2 is present to react.
The answer is A.

agree with this. That was my logic in the exam :)

This was also my logic in the exam.. At region X oxidation would occur, providing electrons for the reduction reaction which would occur in the presence of Oxygen gas, at region Y.. That whats i was thinking

+1
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: herzy on November 15, 2009, 02:09:11 pm
doubt it needs to be said, but 13 had to be A
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: Ilovemathsmeth on November 15, 2009, 06:26:19 pm
I got C as well, positive to positive; negative to negative.

MC was trickier than I thought. Wish I'd allocated more time to it! =(
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: herzy on November 15, 2009, 07:34:55 pm
I had A for question 13 as well. I was very confident with that question as absolutely no O2 was in contact with the iron region.

I also had C for 12 as well (positive - positive, negative-negative).


yeh 12 was positive-positive, negative-negative


I got C as well, positive to positive; negative to negative.

MC was trickier than I thought. Wish I'd allocated more time to it! =(

i agree they were tricky - i thought the whole paper was trickier than people give it credit for...
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: chima987 on November 15, 2009, 07:53:25 pm
for the vanadium question where you had to demonstrate why iron couldn't be used in the vanadium cell i wrote "Vanadium + iron = explosion"
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: herzy on November 15, 2009, 08:05:11 pm
hahahahaha :)
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: methodsboy on November 15, 2009, 09:13:57 pm
I had A for question 13 as well. I was very confident with that question as absolutely no O2 was in contact with the iron region.

I also had C for 12 as well (positive - positive, negative-negative).


yeh 12 was positive-positive, negative-negative


I got C as well, positive to positive; negative to negative.

MC was trickier than I thought. Wish I'd allocated more time to it! =(

i agree they were tricky - i thought the whole paper was trickier than people give it credit for...
yeah. i got C for both q12 and 13
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: herzy on November 15, 2009, 09:52:34 pm
I had A for question 13 as well. I was very confident with that question as absolutely no O2 was in contact with the iron region.

I also had C for 12 as well (positive - positive, negative-negative).

sorry methodsboy, but 13 was A not that it matters now...


yeh 12 was positive-positive, negative-negative


I got C as well, positive to positive; negative to negative.

MC was trickier than I thought. Wish I'd allocated more time to it! =(

i agree they were tricky - i thought the whole paper was trickier than people give it credit for...
yeah. i got C for both q12 and 13
Title: Re: Chemistry Unit 4 Exam Discussion
Post by: /0 on November 26, 2009, 08:32:36 pm
I emailed my chem teacher (who is an assessor), he said fully charged means it's about to discharge.

Oh well, I don't fully agree, but what can you do about it?

Is this his view or what the markers are marking?

I hope they give both.

New word is they will.
=)