ATAR Notes: Forum

VCE Stuff => VCE Science => VCE Mathematics/Science/Technology => VCE Subjects + Help => VCE Chemistry => Topic started by: Ematuro on March 07, 2011, 06:20:05 pm

Title: Atomic Absorption question
Post by: Ematuro on March 07, 2011, 06:20:05 pm
Why are light of different energies absorbed by different elements?
Title: Re: Atomic Absorption question
Post by: burbs on March 07, 2011, 06:23:51 pm
I think it has to do with each element having a different wavelength emitted as it becomes excited.
Title: Re: Atomic Absorption question
Post by: DNAngel on March 07, 2011, 06:52:07 pm
Light of different energies that are absorbed by different elements, are the source of their uniqueness.

That is, each element has a 'fingerprint' in the electromagnetic spectrum, that distinguishes them from other elements.
Title: Re: Atomic Absorption question
Post by: Russ on March 07, 2011, 06:55:16 pm
Why are light of different energies absorbed by different elements?

Different elements have different sets of valence electrons in their subshells. The atom absorbs light and promotes one of those electrons to a higher energy level (excited state). Eventually the energy is released and the atom returns to the ground state. That's why it's different energies for different elements
Title: Re: Atomic Absorption question
Post by: huaxiadragon on March 07, 2011, 07:02:47 pm
Why are light of different energies absorbed by different elements?

Each element has different number of electrons in its outer shell and they are situated in different orbitals. For light to be absorbed, the energy of the light needs to be EXACTLY the difference in energy of the ground state orbit and the excited state.

Since the electron configution of each element is different, the amount of energy each electron absorbs in order to reach excited orbit is different. So that answers your question
Title: Re: Atomic Absorption question
Post by: huaxiadragon on March 07, 2011, 07:03:54 pm
oh man why do people reply ahead of me when I was typing?
Title: Re: Atomic Absorption question
Post by: Mao on March 07, 2011, 07:04:20 pm
Why are light of different energies absorbed by different elements?

Different elements have different sets of valence electrons in their subshells. The atom absorbs light and promotes one of those electrons to a higher energy level (excited state). Eventually the energy is released and the atom returns to the ground state. That's why it's different energies for different elements

Or rather, the subshells are all similarly configured, and electrons fill into the subshells in similar fashion, but the same subshell in different elements have slightly different energies due to the nucleus being different (different charge). This means transitions between subshells have energies unique to an element. Such transition is usually facilitated by absorption or emission of light (where energy is related to wavelength), thus the wavelengths absorbed is unique to an element (i.e. the color absorbed is unique).

@Huaxiadragon, similar correction, I wouldn't go so far as to say valence electrons are in 'different' orbitals. Electrons fill into orbitals in similar fashion (in fact, the ground state configuration is highly predictable). Emission lines/adsorption lines do not so much depend on where the electrons are, but more on the energy level of the orbitals, which change from element to element.