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VCE Stuff => VCE Science => VCE Mathematics/Science/Technology => VCE Subjects + Help => VCE Chemistry => Topic started by: khalil on December 04, 2008, 12:51:27 pm

Title: help; i really need a tutor
Post by: khalil on December 04, 2008, 12:51:27 pm
I dont know where it is just me or some of my holiday hw is really hard.....please help me out

Te is heavier than I, yet it is placed before I in the periodic table. Why?
115L of gas at 455mmHg is heated from 22 degrees to 350K. what is the new pressure?
A car burns 45L of fuel (75% octane and 25% nonane) in a week. What volume of CO(2) does this result in, at SLC.

there is more to come....if u can answer these u are a genius and should become my tutor :)
Title: Re: help; i really need a tutor
Post by: shinny on December 04, 2008, 01:38:01 pm
First question: Periodicity (I think that's what it's called) isn't in the course anymore so I probably don't have the full answer (or perhaps it's not even correct) to this, but I'll do my best. Basically, the periodic table isn't arranged in order of increasing  molar masses. Sure, there's a pattern to it, but as with all sciences, there are always trends, but there are also usually exceptions to these trends. The periodic table is arranged in order of the number of protons an element has, and it just happens that in this case, although Te is heavier, it has a lower number of protons, so it will be placed before 'I'. I can't answer this fully because I'm not sure what all the factors are that contribute to molar mass however, I'm assuming its a case of neutrons here where on average, Te has more neutrons than I, since the relative molar masses given on the periodic tables are averages.

Second question:
The volume and mol of gas are remaining constant, so use the following formula:




Third question: First write the two combustion equations.



Because there is 45L of fuel, and three quarters is octane, then that means 33.75 L is octane, and 11.25 L is nonane. Also, note that because the conditions are remaining constant, and because amount and volume are directly proportional, we can say that;


Add these together to get 371.25 L of carbon dioxide.

And thanks for the offer but I won't be tutoring chemistry =P Check the tutoring forum, there's quite a few quality chem tutors there already. Shivesh (shiveshvarmaxD) and Collin (coblin) are probably the first two that come to mind, and I haven't really heard any complaints about either of them.
Title: Re: help; i really need a tutor
Post by: excal on December 04, 2008, 02:08:46 pm
My only complaint about coblin is that he'll probably mark your work in hot pink.


...not that it's a bad thing :P
Title: Re: help; i really need a tutor
Post by: shinny on December 04, 2008, 02:10:46 pm
Beats red pen I guess. I'm so sick of looking at it after marking my own trial exams so many times.
Title: Re: help; i really need a tutor
Post by: khalil on December 04, 2008, 04:00:30 pm
wow thank u soo much...however in question 2 why did u convert from kelvins to degrees...isnt is always in kelvins...btw ur answer is correct ...i got 539.83mmHg
Title: Re: help; i really need a tutor
Post by: shinny on December 04, 2008, 04:05:42 pm
Now that you mention it, I don't know why I did and like you said, it should be always in Kelvins. Maybe my (and their) answer is wrong and your's is right.
Title: Re: help; i really need a tutor
Post by: khalil on December 04, 2008, 04:09:47 pm
If u dont mind shinditzux, can u help with these :
You are given 5 half cells in each of the following questions. For each, construct
i) the galvanic cell with the HIGHEST voltage possibla and
ii) the galvanic cell with the LOWEST voltage possible
All cells are availible for both galvanic cells

a) Cu/Cu^2+  Ag/Ag^+   Zn/Zn^2+    H(2)/2H^+  Cl(2)/2Cl^-

Also, coblin and shivesh are NOT my tutors because they tutor at the STATE library which is way to far from the southeastern suburbs, plus they charge a whooping $30/hr...THATS HEAPS....theres no point studying in uni..if they tutor for the rest of their lives they will be well off!
Title: Re: help; i really need a tutor
Post by: shinny on December 04, 2008, 04:14:13 pm
$30 sounds very reasonable to me, and I don't think you're going to find quality tutors for much less than that. I could refer you to some of my friends who are starting chemistry tuition next year, but I can't guarantee quality. As for that question, I'm heading out soon so hopefully someone else can do it otherwise I'll probably do it when I get back. It shouldn't be too hard though. Just find the combination which are the furthest apart for i, and closest together for ii. I don't have an electrochemical series on me so I cbf, but it really shouldn't be that difficult.
Title: Re: help; i really need a tutor
Post by: khalil on December 04, 2008, 04:20:21 pm
Yer if u could refer me to ur friends that would be great...that is, if they live around the south eastern suburbs......
Title: Re: help; i really need a tutor
Post by: khalil on December 04, 2008, 04:23:37 pm
Also, for the 3rd question... how did u know that octane and nonane produce water and carbon dioxide when combined with oxygen. Is that like a rule?
answer when u get back :)
Title: Re: help; i really need a tutor
Post by: bturville on December 04, 2008, 04:24:22 pm
Yes, complete combustion of hydrocarbons always produces carbon dioxide and water. If there is not ample oxygen however, expect CO instead of carbon dioxide.
Title: Re: help; i really need a tutor
Post by: khalil on December 04, 2008, 04:26:21 pm
wow, u learn something new everyday
Title: Re: help; i really need a tutor
Post by: khalil on December 04, 2008, 04:37:58 pm
also in stoichometry, i thought u can only deal with the number of moles not amount in litres
Title: Re: help; i really need a tutor
Post by: bturville on December 04, 2008, 04:41:23 pm
You learn in the gases area of study about how moles = litres...at equal temperature and pressures.
Title: Re: help; i really need a tutor
Post by: khalil on December 04, 2008, 05:50:47 pm
i just discovered that in my book rite now..thanks
Title: Re: help; i really need a tutor
Post by: Collin Li on December 04, 2008, 08:37:10 pm
My only complaint about coblin is that he'll probably mark your work in hot pink.


...not that it's a bad thing :P

What? No I don't.
Title: Re: help; i really need a tutor
Post by: khalil on December 12, 2008, 03:53:19 pm
Hey can someone help me with this question:
Draw the stuctural formula of 1,2,3-trimethylbutan-1-ol
the answers have 2 OH's .....dont know if they made a mistake
btw the question is in pg.136 Q8 d in the jacaranda textbook
thanks
Title: Re: help; i really need a tutor
Post by: khalil on December 12, 2008, 05:22:08 pm
Also,
An oxide of iron contains 21.33% oxygen by mass. Find the empirical formula. Ans: Fe(2)O(3)

A compound X is used in ceramic work in the form of its hemihydrate X..5H(2)O which, when mixed with water, gives a solid dihydride X.2H(2)O. If 2.9g of hemihydrate yeilds 3.44g of dihydride, what is the molar mass of the dihydrate X.2H(2)O     Ans, 136

thanks
Title: Re: help; i really need a tutor
Post by: Collin Li on December 12, 2008, 09:46:17 pm
Hey can someone help me with this question:
Draw the stuctural formula of 1,2,3-trimethylbutan-1-ol
the answers have 2 OH's .....dont know if they made a mistake
btw the question is in pg.136 Q8 d in the jacaranda textbook
thanks

That's a pretty weird question already, since that molecule when drawn out should really be named by "pent-" rather than "but-". There are 5 carbons in the longest chain, since there is a methyl group off the end.

Also,
An oxide of iron contains 21.33% oxygen by mass. Find the empirical formula. Ans: Fe(2)O(3)

1 gram of the iron oxide has 0.2133 g of oxygen and 0.7867 g of iron. Divide by their molar masses to reveal:




Note: the fact we chose "1 gram" makes no difference, because we're interested in the ratio between: for the empirical formula, which will be the same regardless of how much grams we worked with to begin with (I arbitrarily chose 1 gram - you could choose 100 if you like).

Anyway: (roughly, is good enough)

Hence is the empirical formula. I disagree with the answers.

A compound X is used in ceramic work in the form of its hemihydrate X..5H(2)O which, when mixed with water, gives a solid dihydride X.2H(2)O. If 2.9g of hemihydrate yeilds 3.44g of dihydride, what is the molar mass of the dihydrate X.2H(2)O     Ans, 136





Since the must balance on both sides of the equation , then they are equimolar:



Since









Once again, the answer is wrong, because we're not done: we want

Crap book.
Title: Re: help; i really need a tutor
Post by: khalil on December 13, 2008, 03:14:24 pm
Thanks Coblin
If a compound is 0.5H(2)O does that mean there is 1 hydrogen? (.5x2)
Title: Re: help; i really need a tutor
Post by: Mao on December 13, 2008, 04:57:56 pm
I'd think it'll be
Title: Re: help; i really need a tutor
Post by: Collin Li on December 13, 2008, 07:52:38 pm
Thanks Coblin
If a compound is 0.5H(2)O does that mean there is 1 hydrogen? (.5x2)

Yes.
Title: Re: help; i really need a tutor
Post by: khalil on December 13, 2008, 07:56:08 pm
Thanks Coblin
If a compound is 0.5H(2)O does that mean there is 1 hydrogen? (.5x2)

Yes.

Is CuSO(4).5H(2)O the same as CuSO(4)H(10)O(2)?
Title: Re: help; i really need a tutor
Post by: Collin Li on December 13, 2008, 08:01:32 pm
Yeah kinda, I think you mean (put all the oxygens together).

The reason why they write it like is to indicate something about its structure, but you don't need to know about that stuff in VCE.
Title: Re: help; i really need a tutor
Post by: dekoyl on December 13, 2008, 08:38:15 pm
Thanks Coblin
If a compound is 0.5H(2)O does that mean there is 1 hydrogen? (.5x2)

Yes.
So there's one hydrogen and.. half an oxygen? Or does it become ?
Title: Re: help; i really need a tutor
Post by: Collin Li on December 13, 2008, 08:40:33 pm
Yeah, it's half an oxygen. But that's not indicative of molecular structure, that's just how the compound is written in this chemical equation. No need to try to make sense of it.

You could similarly write something like: in a chemical equation too.
Title: Re: help; i really need a tutor
Post by: dekoyl on December 13, 2008, 08:43:49 pm
Ah okay thanks Coblin.

I just thought it had to be a whole number (so to multiply all the species by 2 to make it
Title: Re: help; i really need a tutor
Post by: khalil on December 20, 2008, 08:51:01 pm
someone help please
0.148g of a metal carbonate exactly reacts with 20ml of 0.1 M HCL. The formula of the metal carbonate is most likely be:
A. Li(2)CO(3)
B. Na(2)C0(3)
c. MgC0(3)
D. SrC0(3)
Title: Re: help; i really need a tutor
Post by: Mao on December 20, 2008, 09:51:01 pm
write an equation showing the reaction between carbonate and H+, and use the mole ratio to find the number of moles of metal carbonate.

and then use , and see which option matches up.
Title: Re: help; i really need a tutor
Post by: khalil on December 21, 2008, 10:52:22 am
yer thats what the answers state...but i didnt get it!
Title: Re: help; i really need a tutor
Post by: Mao on December 21, 2008, 02:59:18 pm
when the metal carbonate react with HCl



i.e. one mole of carbonate reacts with 2 moles of HCl.

20mL of 0.1M of HCl reacted,

which means that

we know that , transposing gives

now you can match up the correct option by finding the Mr of each.
Title: Re: help; i really need a tutor
Post by: khalil on December 21, 2008, 09:55:44 pm
oh yerrrrrr ...thanks mate
Title: Re: help; i really need a tutor
Post by: khalil on December 28, 2008, 12:55:12 pm
Phosphorous is present in many fertilisers
Phosphorus can be determined gravimetrically by carrying out a numbe of steps, eventually leading to its precipitation as insoluable Mg(2)P(2)0(7). In one such analysis, a 14.298g sample of fertiliser yielded 4.107g of Mg(2)P(2)O(7) precipitate.
(a) Calculate the mass of phosphorous in the precipitate.

I got 1.14g, but the book says 0.8967g.........What the?
Title: Re: help; i really need a tutor
Post by: Rebecca.tutoring on December 28, 2008, 08:01:16 pm
Yeah I got the same as you - maybe you copied down the question wrong, or (more likely) the book could be wrong?
Title: Re: help; i really need a tutor
Post by: khalil on December 28, 2008, 09:55:28 pm
Yeah I got the same as you - maybe you copied down the question wrong, or (more likely) the book could be wrong?
yer maybe the book is wrong...if the book is continuously wrong then what can i rely on? :(
Title: Re: help; i really need a tutor
Post by: Mao on December 29, 2008, 11:12:57 am
Yeah I got the same as you - maybe you copied down the question wrong, or (more likely) the book could be wrong?
yer maybe the book is wrong...if the book is continuously wrong then what can i rely on? :(
I did tell you textbook questions are dodgy :P
Title: Re: help; i really need a tutor
Post by: hard on December 29, 2008, 04:05:14 pm
Yeah I got the same as you - maybe you copied down the question wrong, or (more likely) the book could be wrong?
yer maybe the book is wrong...if the book is continuously wrong then what can i rely on? :(
I did tell you textbook questions are dodgy :P
you can rely on Mao

Title: Re: help; i really need a tutor
Post by: khalil on December 29, 2008, 08:00:30 pm
Yeah I got the same as you - maybe you copied down the question wrong, or (more likely) the book could be wrong?
yer maybe the book is wrong...if the book is continuously wrong then what can i rely on? :(
I did tell you textbook questions are dodgy :P
lol....yer and u said the TSFX ntoes were dodgy....the only thing left to do is checkpoints and theres not many questions there
Title: Re: help; i really need a tutor
Post by: hard on December 29, 2008, 08:32:07 pm
Yeah I got the same as you - maybe you copied down the question wrong, or (more likely) the book could be wrong?
yer maybe the book is wrong...if the book is continuously wrong then what can i rely on? :(
I did tell you textbook questions are dodgy :P
lol....yer and u said the TSFX ntoes were dodgy....the only thing left to do is checkpoints and theres not many questions there
i must agree with the tsfx notes being dodgy. There's no doubting that. 135 for summer school methods and all you pay for is a book of repeated notes that you already have in your text book plus 6 hour lecture to which 90% of it you wouldn't have a clue what's going on as this is all extraterrestrial mumbo jumbo so far. i suggest Access Education. They give you some helpful pointers.
Title: Re: help; i really need a tutor
Post by: Mao on December 29, 2008, 08:36:07 pm
Yeah I got the same as you - maybe you copied down the question wrong, or (more likely) the book could be wrong?
yer maybe the book is wrong...if the book is continuously wrong then what can i rely on? :(
I did tell you textbook questions are dodgy :P
lol....yer and u said the TSFX ntoes were dodgy....the only thing left to do is checkpoints and theres not many questions there
i must agree with the tsfx notes being dodgy. There's no doubting that. 135 for summer school methods and all you pay for is a book of repeated notes that you already have in your text book plus 6 hour lecture to which 90% of it you wouldn't have a clue what's going on as this is all extraterrestrial mumbo jumbo so far. i suggest Access Education. They give you some helpful pointers.

Agreed. TSFX teaches a lot of crap that aren't really on the course.

Access Education, on the other hand, teach you what is actually important. My experiences with them have all been excellent, especially chemistry. One of their chem lecturer, Chris Dwyer, is very awesome, ed_saifa can possibly tell you more =]
Title: Re: help; i really need a tutor
Post by: khalil on December 30, 2008, 08:11:23 pm
Yeah I got the same as you - maybe you copied down the question wrong, or (more likely) the book could be wrong?
yer maybe the book is wrong...if the book is continuously wrong then what can i rely on? :(
I did tell you textbook questions are dodgy :P
lol....yer and u said the TSFX ntoes were dodgy....the only thing left to do is checkpoints and theres not many questions there
i must agree with the tsfx notes being dodgy. There's no doubting that. 135 for summer school methods and all you pay for is a book of repeated notes that you already have in your text book plus 6 hour lecture to which 90% of it you wouldn't have a clue what's going on as this is all extraterrestrial mumbo jumbo so far. i suggest Access Education. They give you some helpful pointers.

Agreed. TSFX teaches a lot of crap that aren't really on the course.

Access Education, on the other hand, teach you what is actually important. My experiences with them have all been excellent, especially chemistry. One of their chem lecturer, Chris Dwyer, is very awesome, ed_saifa can possibly tell you more =]
I will only go to Acess education NOW!
Title: Re: help; i really need a tutor
Post by: hard on December 30, 2008, 08:26:02 pm
Yeah I got the same as you - maybe you copied down the question wrong, or (more likely) the book could be wrong?
yer maybe the book is wrong...if the book is continuously wrong then what can i rely on? :(
I did tell you textbook questions are dodgy :P
lol....yer and u said the TSFX ntoes were dodgy....the only thing left to do is checkpoints and theres not many questions there
i must agree with the tsfx notes being dodgy. There's no doubting that. 135 for summer school methods and all you pay for is a book of repeated notes that you already have in your text book plus 6 hour lecture to which 90% of it you wouldn't have a clue what's going on as this is all extraterrestrial mumbo jumbo so far. i suggest Access Education. They give you some helpful pointers.

Agreed. TSFX teaches a lot of crap that aren't really on the course.

Access Education, on the other hand, teach you what is actually important. My experiences with them have all been excellent, especially chemistry. One of their chem lecturer, Chris Dwyer, is very awesome, ed_saifa can possibly tell you more =]
I will only go to Acess education NOW!
good decision.
Title: Re: help; i really need a tutor
Post by: AQ on December 30, 2008, 08:42:41 pm
oh yerrrrrr ...thanks mate

khalil you only doing 5 subjects all up for vce ??

I wished i stayed at home and prepared for yr 12, make a mistake going on a holiday this yr.
Ow well, im not worried about me falling behind. I cant catch up and im pretty good in chemistry.
Title: Re: help; i really need a tutor
Post by: AQ on December 30, 2008, 08:56:10 pm
I dont know where it is just me or some of my holiday hw is really hard.....please help me out

Te is heavier than I, yet it is placed before I in the periodic table. Why?
115L of gas at 455mmHg is heated from 22 degrees to 350K. what is the new pressure?
A car burns 45L of fuel (75% octane and 25% nonane) in a week. What volume of CO(2) does this result in, at SLC.

there is more to come....if u can answer these u are a genius and should become my tutor :)

khalil dont worry..
I think theres nothing to worry about, you may feel like its hard becuase you havnt learnt it over school or you teacher may have just given it for you to attemp.
If you can't answer a question, best thing to do is leave it aside and move on. Don't ever worry about the question. you can ask your friends over VN (which they are very helpful) or you can ask your teacher.
btw, what school do you go to?
Title: Re: help; i really need a tutor
Post by: khalil on December 30, 2008, 09:34:08 pm
I dont know where it is just me or some of my holiday hw is really hard.....please help me out

Te is heavier than I, yet it is placed before I in the periodic table. Why?
115L of gas at 455mmHg is heated from 22 degrees to 350K. what is the new pressure?
A car burns 45L of fuel (75% octane and 25% nonane) in a week. What volume of CO(2) does this result in, at SLC.

there is more to come....if u can answer these u are a genius and should become my tutor :)

khalil dont worry..
I think theres nothing to worry about, you may feel like its hard becuase you havnt learnt it over school or you teacher may have just given it for you to attemp.
If you can't answer a question, best thing to do is leave it aside and move on. Don't ever worry about the question. you can ask your friends over VN (which they are very helpful) or you can ask your teacher.
btw, what school do you go to?
Yea thanks for the advice, although its not as easy as it seems. If i dont know a question(which happens a lot)....i relli cant be bothered typing up soo much for a simple question to be answered! and sometimes i haev to wait max 2 days. i noe it doesnt seem much but i tend to forget the question i asked to answer! plus my teacher is just as worse as me!
i go to Lyndale SC which is in dandy north (SE region)
im guessing ur turkish?
Title: Re: help; i really need a tutor
Post by: khalil on December 31, 2008, 03:08:37 pm
When talking about standard solutions, how does having a high molar mass minimise errors?
Title: Re: help; i really need a tutor
Post by: Mao on January 01, 2009, 06:16:39 pm
the standard has a known weight, but the importance of this is that you know the number of moles from that weight.

If the standard has a low molar mass, the errors of measurement in weight could mean a huge variation in the number of moles. However, if it had a higher molar mass, the errors of measurement would correspond to a significantly lower variation in the number of moles, hence more accurate.

Think about how accurately you can calculate:
1) how many grains of rice in 1kg bag
2) how many chocolate bars in 1kg bag
Title: Re: help; i really need a tutor
Post by: khalil on June 02, 2009, 08:46:19 pm
A 0.360 g sample of an organic compound containing carbon, hydrogen and oxygen was burnt in excess oxygen. When the gases evolved were passed through anhydrous CaCl2 its mass increased by 0.216 g. The remaining gases, when bubbled through a NaOH solution, increased its mass by 0.528 g. The mass of oxygen in the sample is ...
Title: Re: help; i really need a tutor
Post by: khalil on June 02, 2009, 08:46:50 pm
(c)    Explain how the primary structure of DNA is responsible for the primary structure of a protein.
Title: Re: help; i really need a tutor
Post by: d0minicz on June 02, 2009, 09:39:48 pm
primary structure of DNA is the specific sequence of BASES ; which carries the genetic code => for specific amino acids => specific protein primary structure (sequence of amino acids)
Title: Re: help; i really need a tutor
Post by: TrueTears on June 02, 2009, 09:42:05 pm
Extension: 3 base pairs (a codon) codes for 1 amino acid :)
Title: Re: help; i really need a tutor
Post by: khalil on June 03, 2009, 08:58:55 pm
In the mass spectrum of aspirin, there is a peak at 138. What part of aspirin would this peak be responsible for? I mean if it was for salicyclic acid, then wouldnt it be 137?
Title: Re: help; i really need a tutor
Post by: Mao on June 03, 2009, 10:17:23 pm
Is it a large peak or small peak?

If it is a small peak, it may because of one C13 (isotope of carbon that has a mass of 13) is present in it.
Title: Re: help; i really need a tutor
Post by: khalil on June 04, 2009, 11:12:18 am
Its large, its labelled so im guessing its significant
Title: Re: help; i really need a tutor
Post by: Mao on June 04, 2009, 12:35:59 pm
Salicylic acid's molecular weight is 138.
Title: Re: help; i really need a tutor
Post by: khalil on June 04, 2009, 03:47:01 pm
yer but its not in its full form in aspirin, its H is missing
Title: Re: help; i really need a tutor
Post by: khalil on June 04, 2009, 06:31:17 pm
Also, are disaccharides solid? How can you tell. There was a VCAA question on this
Title: Re: help; i really need a tutor
Post by: khalil on June 04, 2009, 06:37:10 pm
VCAA says that Q5aiii is glucose...is this true?
http://www.vcaa.vic.edu.au/vce/studies/chemistry/assessreports/2005/chemistryassessreportnov05.pdf
Title: Re: help; i really need a tutor
Post by: Mao on June 04, 2009, 09:10:16 pm
yer but its not in its full form in aspirin, its H is missing

An H. radical may join on to the m/e=137 ion. It is possible

Also, are disaccharides solid? How can you tell. There was a VCAA question on this

table sugar is a disaccharide


Title: Re: help; i really need a tutor
Post by: khalil on June 05, 2009, 05:18:00 pm
more energy is required to vibrate:
a) C-C compared to C=C            b) C-Cl compared to C-Br            c) C-O compared to C-H           d)C=C compared to C=-C (triple bond)
Title: Re: help; i really need a tutor
Post by: Mao on June 05, 2009, 06:22:59 pm
Looking at bond strengths:

C=C > C-C
C-Cl > C-Br [Cl is more electronegative hence pulls closer]
C-O > C-H
C=C > C=C

Greater bond strength requires greater energy