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VCE Stuff => VCE Science => VCE Mathematics/Science/Technology => VCE Subjects + Help => VCE Chemistry => Topic started by: VCE_2012 on June 10, 2012, 10:56:26 pm

Title: "Identify the 2 functional groups that are formed..."
Post by: VCE_2012 on June 10, 2012, 10:56:26 pm
Question on the 2011 VCAA (Q8 b)
"Identify the 2 functional groups that are formed as a result of the hydrolysis of the peptide link."
My answer was Amine group and carboxyl group.
However one of the VCCA answer was amino (not amine)==> would I still be technically correct? 
Title: Re: "Identify the 2 functional groups that are formed..."
Post by: ecvkcuf on June 10, 2012, 10:58:29 pm
Yes you would be correct.
Title: Re: "Identify the 2 functional groups that are formed..."
Post by: ligands on June 10, 2012, 10:59:44 pm
I imagine peptide linkage would be correct aswell ( not 100% tho )
Title: Re: "Identify the 2 functional groups that are formed..."
Post by: ggxoxo on June 10, 2012, 11:12:32 pm
I imagine peptide linkage would be correct aswell ( not 100% tho )

 I think we're eliminating the peptide linkages via hydrolysis
Title: Re: "Identify the 2 functional groups that are formed..."
Post by: oneoneoneone on June 10, 2012, 11:17:07 pm
The proper name for the functional group is the amino functional group so i'm not sure if they'd pay it. Its like if you called it an 'oic acid' group.
Title: Re: "Identify the 2 functional groups that are formed..."
Post by: ecvkcuf on June 10, 2012, 11:24:15 pm
The proper name for the functional group is the amino functional group so i'm not sure if they'd pay it. Its like if you called it an 'oic acid' group.

No I don't think you can equate the two.. amine and amino refer to the same functional group whilst 'oic acid' refers to a carboxylic acid.
Title: Re: "Identify the 2 functional groups that are formed..."
Post by: oneoneoneone on June 10, 2012, 11:28:39 pm
Calling it a carboxylic acid functional group is also kind of wrong. My point is that functional groups are named after their prefix names (hydroxy, carboxy, amino) etc.
Title: Re: "Identify the 2 functional groups that are formed..."
Post by: charmanderp on June 10, 2012, 11:38:46 pm
Both amino and amine are legitimate names for the functional group. It doesn't have to do strictly with their prefixes.
Title: Re: "Identify the 2 functional groups that are formed..."
Post by: nisha on June 11, 2012, 09:58:03 am
Both amino and amine are legitimate names for the functional group. It doesn't have to do strictly with their prefixes.

Amine refers to the family, while amino is the functional group. If you called the functional group an amine group, that is just like calling another functional group an "alcohol" functional group instead of a hydroxy/hydroxyl functional group.
I'm pretty sure they are quite picky with the names.
Title: Re: "Identify the 2 functional groups that are formed..."
Post by: charmanderp on June 11, 2012, 11:15:33 am
Both amino and amine are legitimate names for the functional group. It doesn't have to do strictly with their prefixes.

Amine refers to the family, while amino is the functional group. If you called the functional group an amine group, that is just like calling another functional group an "alcohol" functional group instead of a hydroxy/hydroxyl functional group.
I'm pretty sure they are quite picky with the names.

That's that case with alcohols but not with this, I'm almost one hundred percent sure.

And it's completely different to alcohols because in that case hydroxyl refers to the OH group, whereas alcohol does not, because an alcohol is a type of substance.
Title: Re: "Identify the 2 functional groups that are formed..."
Post by: Lasercookie on June 11, 2012, 12:07:46 pm
VCAA 2009 Assessor Report Question 8bi sheds a bit of light on the difference between amine and amino:

Quote
Compounds in which the principal functional group is the –NH2 – are called amines and so ‘amine’ should appear in the
systematic name. Hence, names such as 1-amino-3-methylbutane are not systematic names. The term ‘amino’ is used in
compounds which contain –NH2 and a functional group of higher priority, e.g. –COOH in amino acids.
http://www.vcaa.vic.edu.au/vcaa/vce/studies/chemistry/assessreports/2009/chemistry_assessrep_june09.pdf

That's in terms of systematic naming though. So for the name of the functional group, usage depends on what the molecule actually is?
Title: Re: "Identify the 2 functional groups that are formed..."
Post by: charmanderp on June 11, 2012, 12:41:03 pm
I personally always say amino but I'm almost certain it's not incorrect to say amine.