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VCE Stuff => VCE Science => VCE Mathematics/Science/Technology => VCE Subjects + Help => VCE Chemistry => Topic started by: kenhung123 on June 23, 2010, 12:37:24 am

Title: Implication of heat content
Post by: kenhung123 on June 23, 2010, 12:37:24 am
So when the change in heat content of reactants and products is negative/positive, could we say there is a net loss (negative) or net gain (positive) of energy in the chemical reaction? (assuming the enclosed system is not part of the chemical reaction?)
Title: Re: Implication of heat content
Post by: Mao on June 23, 2010, 01:45:07 am
You mean if the change in enthalpy of the system (reactants and products) is negative, the surroundings must have gained energy, and vice versa.
Title: Re: Implication of heat content
Post by: kenhung123 on June 23, 2010, 07:26:15 am
Umm yea, but alternatively could you say the chemical reaction results in a net production of heat in an exothermic?
Title: Re: Implication of heat content
Post by: Martoman on June 23, 2010, 04:38:13 pm
if its negative think of the thing as losing heat, and if it loses heat then it must give it off in some way. This is always exothermic.

Obviously the converse holds. If there is a net gain of heat then the product has gained heat. This must mean it absorbed it from somewhere, usually in the solvent it is reacting in (think of the ice packs the afl use to treat injuries the "snap" ones, they are endothermic as they absorb heat).