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VCE Stuff => VCE Science => VCE Mathematics/Science/Technology => VCE Subjects + Help => VCE Chemistry => Topic started by: jasoN- on October 11, 2010, 03:51:45 pm

Title: Buffers
Post by: jasoN- on October 11, 2010, 03:51:45 pm
Can someone explain to me (in detail if possible) how buffers work
Also to what extent do we need to understand buffers for the exam?
All help appreciated,
Thanks
Title: Re: Buffers
Post by: samiira on October 11, 2010, 04:42:56 pm
A buffer is simply a mixture of a weak acid and its conjugate base or a weak base and its conjugate acid. Buffers work by reacting with any added acid or base to control the pH. For example, let's consider the action of a buffer composed of the weak base ammonia, NH3, and its conjugate acid, NH4 +. When HCl is added to that buffer, the NH3 "soaks up" the acid's proton to become NH4 +. Because that proton is locked up in the ammonium ion, it proton does not serve to significantly increase the pH of the solution. When NaOH is added to the same buffer, the ammonium ion donates a proton to the base to become ammonia and water. Here the buffer also serves to neutralize the base.

As the above example shows, a buffer works by replacing a strong acid or base with a weak one. The strong acid's proton is replaced by ammonium ion, a weak acid. The strong base OH- was replaced by the weak base ammonia. These replacements of strong acids and bases for weaker ones give buffers their extraordinary ability to moderate pH.