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VCE Stuff => VCE Science => VCE Mathematics/Science/Technology => VCE Subjects + Help => VCE Chemistry => Topic started by: shinny on June 10, 2008, 09:25:52 pm

Title: Hydroxyl group
Post by: shinny on June 10, 2008, 09:25:52 pm
Can -OH only be classified as a hydroxyl if it is by itself and not as part of a carboxylic acid? I've seen some sources where they classify an -OH part of a carboxylic acid as still a hydroxyl group, but other sources dont. and when does -OH become only a hydroxyl rather than an alcohol group? (i.e. use the 1-hydroxy. etc notation rather than ethan-1-ol notation.)
Title: Re: Hydroxyl group
Post by: Collin Li on June 10, 2008, 09:30:46 pm
-OH should not be considered a hydroxyl group if it is also connected to a C=O

Similar thing with the ether link versus the ester link.
Title: Re: Hydroxyl group
Post by: Mao on June 10, 2008, 09:35:42 pm
Can -OH only be classified as a hydroxyl if it is by itself and not as part of a carboxylic acid? I've seen some sources where they classify an -OH part of a carboxylic acid as still a hydroxyl group, but other sources dont. and when does -OH become only a hydroxyl rather than an alcohol group? (i.e. use the 1-hydroxy. etc notation rather than ethan-1-ol notation.)

alcohol group doesnt exist, its called hydroxy.

and "-hydroxy" is used instead of "-ol"in functional group hierarchy. i.e. carboxyl group take predecence over hydroxy, hence in a molecule with both the hydroxy has to be suffix whilst the carboxyl is indicated in the suffix. [not on course]

and, there is no "carboxylic acid" functional group