Rule of thumb: Always find the number of mol with the stuff that you can find first.
First write the equation.
1. CH3COOH (aq) + NaOH (aq) -> CH3COONa (aq) + H2O (l) (for some reason I've always seen ionic compounds with CH3COO that have the cation written at the back)
Next, find the number of mol of NaOH with the formula n = cv.
2. n(NaOH) = 0.102 x 0.01982 = 0.002022 mol
Next, find the number of mol of CH3COOH using the molar ratios.
3.n(CH3COOH)aliquot = 1/1 x 0.002022 = 0.002022 mol
Work out the concentration of the 20.00 mL CH3COOH aliquot by rearranging n=cv.
4. [CH3COOH] = n/v = 0.002022/0.02 = 0.101082 M
Use the dilution formula (c1v1=c2v2) to find out the original concentration of the 20.00 mL sample.
5. c1 = c2xv2/v1 = 0.101082 x 250/20 = 1.26M
Water is not really mixed with vinegar, but rather it dilutes its concentration so that it will be lower during the titration.