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November 01, 2025, 12:36:03 pm

Author Topic: Glc  (Read 491 times)  Share 

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sam0001

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Glc
« on: May 28, 2012, 08:18:18 pm »
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In terms of GLC, which is more important, the attraction to the stationary phase or volatility?

Tonychet2

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Re: Glc
« Reply #1 on: May 28, 2012, 08:39:16 pm »
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the less volatile the substance the more likely it will bond to the stationary phase if it is polar . . .

volatility decreases with increasing chain length
volatility decreases with stronger bonding e.g hydrogen bonding in alcohols