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October 21, 2025, 07:14:16 pm

Author Topic: Galvanic Cells  (Read 943 times)  Share 

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Funkyy007

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Galvanic Cells
« on: September 04, 2012, 06:43:36 pm »
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In a Galvanic Cell, why is the electrode metal and the electrolyte solution made up of the same element?
E.g Cu/Cu2+


What would happen if they are made up of two different elements? For example the Electrode is made up of Zinc metal and the Electrolye solution is made up of Copper solution?

Jenny_2108

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Re: Galvanic Cells
« Reply #1 on: September 05, 2012, 09:51:51 pm »
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In a Galvanic Cell, why is the electrode metal and the electrolyte solution made up of the same element?
E.g Cu/Cu2+


What would happen if they are made up of two different elements? For example the Electrode is made up of Zinc metal and the Electrolye solution is made up of Copper solution?

Because they need to form conjugate redox pairs


k0k0p0p

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Re: Galvanic Cells
« Reply #2 on: September 20, 2012, 11:27:37 pm »
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The metals used are the same base element to avoid the electrolyte and the electrode reacting with each other and inhibiting the function of the cell.

Cells with different electrolytes and electrodes do exist, such as a specific plating cell I forget the name of.
However, if a cell has a zinc electrode and a copper electrolyte (assuming these do not react and will plate a key sitting in the electrolyte) the key will be plated with copper for a time as the copper comes out of solution. However, soon there will be more zinc coming into solution than there is copper in solution. Due to this the zinc will be plated on top of the copper which is on top of the key. (I am not sure if this arrangement would actually work).
This technique is used in cells such as jewellery plating cells to get coatings of two different types of metals on the jewellery.

Essentially, the same metal is used for the electrode and electrolyte to maintain consistency across the plating and solution.