Normally you'd make another vector, lets say

, then for the two vectors to be perpendicular, the dot product of the two vectors should be zero. As we want a unit vector, the magnitude of this new vector should be

, i.e.

, i.e.

.
The problem is we have three unknowns and only two equations/pieces of information. This is because we only have a single vector that we're given, so there is more than one unit vector that is perpendicular to it, i.e. there is a set of vectors in a plane that is perpendicular to the vector. You could solve the two equations in terms of a parameter but it looks like more effort than it's worth for this question, (if it were not VCE maths I'd say something different here though

).
i.e. When we have a single vector, all the vectors in that plane will be perpendicular to the vector we're given.
Normally with these problems we'd have two vectors, and be asked to find a unit vector perpendicular to both, which would lock it down into one or two vectors (the second including a unit vector in the opposite direction to the first).
In this case it's probably easier to just take the dot product of the MC options with the vector you have, and choose the one that gives zero.
Anyways, if you are asked for the vector perpendicular to
two vectors that you're given, then you'd do this.
1.

.
2. Take the dot product of

and the first vector, set it to zero (as they are prependicular) and form equation [1].
3. Take the dot product of

and the second vector, set it to zero (as they are perpendicular) and form equation [2]/=.
4. As we have a unit vector, the magnitude is one, so


5. Solve the three equations simultaneously.