Login

Welcome, Guest. Please login or register.

November 01, 2025, 12:48:34 pm

Author Topic: oxidation of glycerol  (Read 620 times)  Share 

0 Members and 1 Guest are viewing this topic.

bridgetmaude

  • Victorian
  • Fresh Poster
  • *
  • Posts: 1
  • Respect: 0
  • School: GVGS
oxidation of glycerol
« on: May 28, 2015, 10:56:40 pm »
0
I was wondering if anyone knows what happens to glycerol when it is oxidised with KMnO4? do all 3 OH groups become carboxyl groups?
Thanks so much if you can help me out  :)

lzxnl

  • Victorian
  • ATAR Notes Legend
  • *******
  • Posts: 3432
  • Respect: +215
Re: oxidation of glycerol
« Reply #1 on: May 29, 2015, 09:54:15 am »
0
I was wondering if anyone knows what happens to glycerol when it is oxidised with KMnO4? do all 3 OH groups become carboxyl groups?
Thanks so much if you can help me out  :)

Let me just ask you this. Can you imagine the C2 alcohol group ever being replaced by a carboxylic acid group? It's not possible because that carbon is bonded to two other carbons yet a COOH group requires three bonds to non-carbon atoms. The C2 doesn't have enough spare bonds for that.
Instead, you're going to oxidise the C1 and C3 alcohols to carboxylic acids and the C2 alcohol will become a ketone.
2012
Mathematical Methods (50) Chinese SL (45~52)

2013
English Language (50) Chemistry (50) Specialist Mathematics (49~54.9) Physics (49) UMEP Physics (96%) ATAR 99.95

2014-2016: University of Melbourne, Bachelor of Science, Diploma in Mathematical Sciences (Applied Maths)

2017-2018: Master of Science (Applied Mathematics)

2019-2024: PhD, MIT (Applied Mathematics)

Accepting students for VCE tutoring in Maths Methods, Specialist Maths and Physics! (and university maths/physics too) PM for more details