Further Maths likes to keep things relatively simple and works on loans or investments where calculations and payments are made at the END of each period. This is the more usual practice in life.
In some instances, in the financial world, there is some advantage for payments to be made at the START of a period. For example, a person taking an investment loan beginning in June might choose to make a payment before the end of June so that a tax deduction can be made in the same financial year (July to June) as the loan was taken. (They might even make this payment on the same day they actually take out the loan. They payment has to be made anyway, so why not do it when you can get a tax break?)
For your needs in Further, consider only interest calculations and payments being made at the end of each period. Therefore, use PMT:END