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November 01, 2025, 12:36:54 pm

Author Topic: Enthalpy H2S2O7+H2O=>2H2SO4  (Read 4254 times)  Share 

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kenhung123

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Enthalpy H2S2O7+H2O=>2H2SO4
« on: August 22, 2010, 11:50:10 am »
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Is this reaction exo or endo?

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Re: Enthalpy H2S2O7+H2O=>2H2SO4
« Reply #1 on: August 22, 2010, 12:19:46 pm »
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As far as i know, this reaction is a simple dilution and no energy is produced or absorbed. And i can't find an enthalpy value for it anywhere, so it's neither exo nor endo
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kenhung123

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Re: Enthalpy H2S2O7+H2O=>2H2SO4
« Reply #2 on: August 22, 2010, 12:39:42 pm »
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Yea but SO3+H2O=H2SO4 is also dilution and is exo though

happyhappyland

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Re: Enthalpy H2S2O7+H2O=>2H2SO4
« Reply #3 on: August 22, 2010, 12:46:52 pm »
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its exothermic.

Its not a dilution.

SO3 + H2O = H2SO4 releases too much energy thus the sulfuric acid forms into a mist which is too hard to collect therefore we split this equation in to 2 and effectively you split the energy released. Lets call energy released here amount "C"

So we put it into two equations the first being
SO3 + H2SO4= H2S2O7 ENERGY IS RELEASED but less than "C" so lets call it "A"

Then
H2S2O7 + H2O = 2H2SO4 energy again is released but ALSO less than "C" so no mist of h2so4 is formed Call energy released "B"

A + B must = C. but by splitting up the equation you allow less heat generated in such short amount of time.
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kenhung123

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Re: Enthalpy H2S2O7+H2O=>2H2SO4
« Reply #4 on: August 22, 2010, 12:55:42 pm »
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Wow that was very intelligent of you to figure that out. Thanks.
Is the chamber which H2S2O7+H2O not called the diluter?

superflya

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Re: Enthalpy H2S2O7+H2O=>2H2SO4
« Reply #5 on: August 22, 2010, 01:21:44 pm »
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dilution tower?? the oleum is simply hydrated to produce sulfuric acid, dont know where u got dilution tower from :/
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Re: Enthalpy H2S2O7+H2O=>2H2SO4
« Reply #6 on: August 22, 2010, 01:41:48 pm »
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Ok thanks

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Re: Enthalpy H2S2O7+H2O=>2H2SO4
« Reply #7 on: August 23, 2010, 04:48:43 pm »
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Yeah it is called the diluter.
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