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November 01, 2025, 11:15:49 am

Author Topic: Hydroxyl group  (Read 1025 times)  Share 

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shinny

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Hydroxyl group
« on: June 10, 2008, 09:25:52 pm »
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Can -OH only be classified as a hydroxyl if it is by itself and not as part of a carboxylic acid? I've seen some sources where they classify an -OH part of a carboxylic acid as still a hydroxyl group, but other sources dont. and when does -OH become only a hydroxyl rather than an alcohol group? (i.e. use the 1-hydroxy. etc notation rather than ethan-1-ol notation.)
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Collin Li

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Re: Hydroxyl group
« Reply #1 on: June 10, 2008, 09:30:46 pm »
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-OH should not be considered a hydroxyl group if it is also connected to a C=O

Similar thing with the ether link versus the ester link.

Mao

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Re: Hydroxyl group
« Reply #2 on: June 10, 2008, 09:35:42 pm »
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Can -OH only be classified as a hydroxyl if it is by itself and not as part of a carboxylic acid? I've seen some sources where they classify an -OH part of a carboxylic acid as still a hydroxyl group, but other sources dont. and when does -OH become only a hydroxyl rather than an alcohol group? (i.e. use the 1-hydroxy. etc notation rather than ethan-1-ol notation.)

alcohol group doesnt exist, its called hydroxy.

and "-hydroxy" is used instead of "-ol"in functional group hierarchy. i.e. carboxyl group take predecence over hydroxy, hence in a molecule with both the hydroxy has to be suffix whilst the carboxyl is indicated in the suffix. [not on course]

and, there is no "carboxylic acid" functional group
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