Questions:
1. (this one is quite trivial but nonetheless) After the cracking of a crude oil fraction, one of the products is found to be a gas at room temperature. The substance is also a hydrocarbon containing 85.71% carbon by mass. Name one product from the cracking process.
I worked out the empirical formula to be

but I don't see how this relates to the question. Crude oil can crack into heaps of different smaller hydrocarbons, but I don't know the chemical formula of crude oil so how do I know what one product it cracks into?
2. The mass spectrum of

contains a peak at 27, what would this peak be?
I think its

, but can it also be

?
3. Say you got an amino acid, when it's placed in an acidic solution heinemann says this form is the most abundant

, where Z is a side chain. However say you got this amino acid:

Does the

in the side chain (
_3)
) also get turned into a

or just the one that's on the first(

) carbon?