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May 14, 2024, 05:31:36 pm

Author Topic: Battery equations?  (Read 636 times)  Share 

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impulsebro89

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Battery equations?
« on: October 28, 2018, 09:57:58 am »
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Hello!
Can someone check to see whether my battery equations are correct or not? I've seen so many iterations of these equations that I don't know what's real anymore  :o

Button cell
Anode: Zn(s) + 2OH-(aq)- --> ZnO(s) + H2O(l) + 2e-
Cathode: Ag2O(s) + H2O (l) + 2e- --> 2Ag(s) + 2OH-(aq)
Overall: Zn(s) + Ag2O(s) --> ZnO(s) + 2Ag(s)

Dry Cell
Anode: Zn(s) --> Zn2+(aq) + 2e-
Cathode: 2MnO2(aq) + 2H+ + 2e- --> Mn2O3(aq) + H2O(l)
Overall: ?

For the dry cell I've seen so many versions of the cathode; is it ok to write this one down in the exam? Also what is the overall equation for it?

Thanks
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infinityandbeyond

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Re: Battery equations?
« Reply #1 on: October 28, 2018, 11:04:02 am »
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I guess if you got that from a reliable source, the examiners will accept it. I believe they will accept many forms of the half equations.

The overall equation for dry cell is:
Zn(s) + 2MnO2(aq) + 2H+--> Zn2+(aq) Mn2O3(aq) + H2O(l)

Simply just integrate the cathode and anode half equations together, cancelling 2e- from both sides.

impulsebro89

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Re: Battery equations?
« Reply #2 on: October 28, 2018, 11:25:58 am »
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Cool thanks! I wasn't sure if that overall equation was correct or not because the cathode equation for the dry cell is like a simplified version without the spectator ions.

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ATAR: 97.00