Okay, I think I understand the apparent problem. While one point on the PPF will give the greatest number of total goods and services, this is a SEPARATE concept to technical efficiency, which is merely how many outputs of a particular good or service you get after putting a certain number of resources into the production process.
So take an example of a hypothetical economy that could only produce strawberries or fountain pens. As we know, the more they produce of one good, the less they can produce of the other good. And while there will be an optimal point somewhere along the curve where the greatest volume of the two goods combined will be achieved, the land, labour and capital resources that are being used to create these goods are being used to the same efficiency regardless of how many of each good are being produced. The workers and machines producing the fountain pens are experiencing the same technical efficiency regardless of whether they end up producing 1,000 or 5,000 fountain pens and same for the strawberries. It's just a different concept.
It all comes down to which tpye of efficiency we're talking about. Technical efficiency is very different from allocative efficiency (the main, big definition of efficiency - an allocation of resources that maximises the satisfaction of society) for example.