Login

Welcome, Guest. Please login or register.

June 18, 2024, 02:16:28 am

Author Topic: Equilibrium Question  (Read 636 times)  Share 

0 Members and 1 Guest are viewing this topic.

4231

  • Victorian
  • Forum Regular
  • **
  • Posts: 59
  • Respect: 0
Equilibrium Question
« on: August 17, 2011, 02:55:59 pm »
0
If you dilute a solution with unequal reactants and and products, does the equilibrium change?
I know as soon as you dilute it, all the concentrations decrease, but does the equilibrium shift to the side with more particles?
Thanks  ;D

Vincezor

  • Victorian
  • Forum Obsessive
  • ***
  • Posts: 332
  • Respect: +11
  • School: Glen Waverley Secondary College
  • School Grad Year: 2011
Re: Equilibrium Question
« Reply #1 on: August 17, 2011, 04:11:37 pm »
0
The equilibrium constant does not change, as this has been "scientifically proven" (I think I read this somewhere, anyway) to be only affected by temperature.

However, when diluted, the system is no longer in equilibrium and thus will cause a shift in the direction of more particles.

2010: Systems Engineering 44            

2011: Specialist Mathematics 37 | Mathematical Methods (CAS) 43 | Physics 39 | Chemistry 42 | English 41

ATAR: 98.50

2012: Eng/Law @ Monash

azn_dj

  • Victorian
  • Forum Obsessive
  • ***
  • Posts: 219
  • Respect: +29
  • School: Melbourne High School
  • School Grad Year: 2010
Re: Equilibrium Question
« Reply #2 on: August 17, 2011, 11:23:53 pm »
0
The whole point of the equilibrium constant IS because it doesnt change!

The equilibrium constant will tell you what the NEW concentrations are. If you change the constant, then you kinda screw up your calculations.
2009: Biology
2010: Math Methods CAS, Specialist Maths, Chemistry, English.
2011: Bachelor of Commerce/Engineering Monash University Clayton.

English Teacher at Chambers Institute.
Privately tutoring Maths, Chemistry.

HenryP

  • Victorian
  • Forum Regular
  • **
  • Posts: 67
  • Respect: +1
Re: Equilibrium Question
« Reply #3 on: August 17, 2011, 11:34:47 pm »
0
This is a tricky question as the amount of products and reactants you are adding differs. The shift may not necessarily go to the side with more particles.
Say for example that the side with more particles is the side with products and you add an excessive amount of products and only a few reactants to the mixture, the mixture may shift towards the reactants as the amount of products is far greater than the reactants, despite it being the products being the side with more particles.
However if you dilute with water the mixture will shift towards the side with more particles.
Hope that made sense...
2010: Accounting [38]
2011: Chemistry [30+] | Physics [30+] | Methods (CAS) [30+] | Specialist [30+] | English [25+]
ATAR : Hopefully 60+
UMAT: 28 Percentile
2012: PhB - Science (ANU)