For the inverse, because it is a 3x3 matrix, you aren't expected to find it without technology. So type the matrix into your calculator and raise it to -1 to find the inverse.
For the inverse to not exist, the determinant must equal 0. You can either find the determinant using your calculator and solve it to equal 0, or you can have a look at the elements in the inverse matrix you found before. Ask yourself, when will these elements be undefined? Ie, for what values of a are the elements dividing by zero?
You'll find there will be two values. For the next question, the way I would do it is to solve the equations with your calculator using both values of a that we found. One will give you the result "false", meaning the equations have no solution, and one will give you an answer in terms of another parameter, meaning there are infinite solutions.