Hint for 14a. Rotate each line individually about the x axis, find the separate volumes and then add them up.
The equations of the lines are y=x/a and y=(x-1)/(a-1). For each line, the integral is pi*y^2 dx integrated over whatever x values they take, so [0,a] for the first line and [a,1] for the second line. Work out the integrals from that.
I wouldn't even bother doing that for the second question. Note that if you draw it out, you're revolving a straight line that intersects the axes. Therefore you get a cone that is easy to picture. Its radius is (1-k^2)^1/2 from the y-coordinate and its height is k. Its volume is hence 1/3*pi*(1-k^2)*k. Differentiate this, set the derivative to zero, prove that it's a local maximum...you get the drill.