consider the unit circle. select a point in the first quadrant on the circumference of the unit circle. connect this point to the origin (i.e. centre of the unit circle). let the angle between the radius that you just drew and the positive direction of the x-axis be θ. then the point on the circumference of the unit circle would have coordinates (cosθ, sinθ). pay careful attention to the implications of this; this means that cosθ corresponds to the x-coordinate, and sinθ corresponds to the y-axis. these are the unit circle definitions of sine and cosine.
with the unit circle definitions of sine and cosine in mind, you can derive all trigonometric identities. consider the following question:
simplify sin(pi - θ).
okay, what do we do? first of all let's draw the angle pi - θ. if θ is in the first quadrant, then pi - θ should be in the second quadrant. the point on the circumference is (cos(pi - θ), sin(pi - θ)). let us focus on the y-coordinate. physically draw in this y-coordinate. what do you notice about the value of this y-coordinate, and that of the y-coordinate of the original point (cos(θ), sin(θ))? that's right, the values are exactly the same. how do we know that? congruent triangles.
so we conclude that sin(pi - θ) = sin(θ). all the symmetry properties, etc. can be proven in a similar way.