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November 01, 2025, 01:19:56 pm

Author Topic: Checkpoint Question  (Read 659 times)  Share 

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sin0001

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Checkpoint Question
« on: September 19, 2012, 10:02:56 pm »
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20 mL slutions of 0.1M concentration of Sulfuric acid, Nitric acid and Ethanoic acid are seperately titrated with 0.1M of NaOH. In order to react completely:
A: all three acids would require the same amount of NaOH
B: Nitric acid woud require more NaOH than ethanoic acid but less than Sulfuric acid
C: Sulfuric acid and Nitric acid would require the same amount of NaOH but ethanoic acid would require less
D: Ethanoic acid and Nitric acid would require the same amount of NaOH, but sulfuric acid would require more

The answer is D, but can someone explain why ethanoic acid and nitric acid require the same amount, i get that they are monoprotic acids and sulfuric acid is diprotic, but in reality, ethanoic acid and nitric acid of same concentration would produce very different amounts of H+ ions, because of their different Ka values and they would ionise to different extents. Isn't the NaOH reacting with the H+ ions, so more ethanoic acid should be needed to produce H+ needed for the reaction, because it ionises to a lesser extent.
Isn't this supposed to a Unit 3 questin lol
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Conic

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Re: Checkpoint Question
« Reply #1 on: September 21, 2012, 11:28:01 pm »
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It's an acid-base reaction, not dissociation. The strength doesn't matter as far as i know.
2012-13: VCE at Parade College (Chemistry, English, Mathematical Methods, Physics and Specialist Mathematics).
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remo

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Re: Checkpoint Question
« Reply #2 on: September 21, 2012, 11:48:37 pm »
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HNO3 and Ethanoic acid are both monoprotic and in equal concentrations. Former is strong and latter is weak. However, when titrating they would require the same NaOH as they would yield the same H ions till the equivalence point. When you are reacting NaOH with ethanoic acid you would be removing H ions from the system causing it to shift to the right until no H ions remain. This would be the equivalent to when no H ions remain for the HN03 and NaOH titration.

A bit muddled soz.

Conic

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Re: Checkpoint Question
« Reply #3 on: September 22, 2012, 01:34:54 pm »
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Isn't this supposed to a Unit 3 questin lol
I think it's assumed knowledge from Unit 1 and 2 rather than Unit 4.
2012-13: VCE at Parade College (Chemistry, English, Mathematical Methods, Physics and Specialist Mathematics).
2014-16: Bachelor of Science at La Trobe University (Mathematics and Statistics).
2017-17: Bachelor of Science (Honours) at La Trobe University (Mathematics).
2018-21: PhD at La Trobe University (Mathematics).