Hey guys, just some help with NEAP 2008 qn 2.
I thought that in an equilibrium, the rate of the forward reaction is equal to the rate of the backward reaction . Just clarifying the provided answer of A - isn't R and Q technically being formed/disappearing at the same "rate" but it takes Q four times longer to disappear because there is 4 times as much of it?
Rate of reaction is different to the rate of formation or rate of disappearance of some quantity. It's defined as essentially the rate of formation of a product (or consumption of a reactant) divided by its stoichiometric coefficient. In your example, the rate of reaction is the same as the rate of production of R, or half the rate of production of S, or a quarter of the rate of consumption of Q.
In this question, let's consider what happens when one molecule of R is formed. You needed two molecules of P and four molecules of Q. Can you see that per reaction, the amount of Q used up is four times the amount of R produced?