Hi guys!
I could really use some help! I really appreciate it

In volumetric analysis, the properties of the reactants, as well as the nature of the reaction between them, will determine if a back titration is to be used. Consider the following cases:
I. The substance being analysed is volatile
II The substance being analysed is insoluble in water but it is soluble in dilute acid
III The end point of the reaction is difficult to detect.
In which cases would a back titration be more suitable than a simple forward titration?
The answer is I, II, and III (all the above)
Could someone please explain to me WHY (for each I, II and III)? I don't get why it would be more suitable for back titration. Why wouldn't it not be feasible to do a forward titration?
Another question is:
Consider the following unbalanced ionic equation.
Hg(l) + Cr
2O
72- (aq) + H
+ (aq) --> Hg
2+(aq) + Cr
3+(aq) +H
2O (l)
When this equation is completely balanced, the coefficient of Hg (l) will be:
A. 1
B. 2
C. 3
D. 4
I tried just balancing atoms (disregarding the charges) and I got A
So then I took the charges into account and then I got B
The correct answer is C
Could you please explain how it is C? (and not A or B)
Thanks so much!!
