Could someone please explain how exactly pressure affects an equilibrium system? I understand that the system will adjust to the increased pressure according to Le Chatelier's principle, but I'm not exactly sure how it actually happens.
Thanks
Let's say we have an increase in pressure / a decrease in volume. What that means is that now, in a given space, there are more reactant/product particles. According to Le Chatelier's principle, there will be either a net forward or net backward reaction to oppose this change, i.e. to decrease the pressure or reduce the number of particles in a given space. To do this, the equilibrium will shift towards the direction with the fewer particles. For example, if we were looking at the reaction 2H
2(g) + O
2(g) -> 2H
2O(g), the system would respond to an increase in pressure with a net forward reaction, as this would take three particles and make only two particles. On the other hand, when there is a decrease in pressure / an increase in volume, there will be a net reaction in the direction that produces more particles. This could be either the forward or backward direction, it depends on the specific reaction.
Does this make sense?