Rhubarb is a plant with edible pink stems or stalks. The rhubarb stalks are pink because the epidermal cells contain a pink pigment. The pink pigment is packaged within the cell in the large vacuole that occupies most of the volume of the cell.
The pigment is a type of molecule called an anthocyanin. These molecules are relatively large and consist of three hydrocarbon rings to which sugar molecules are bonded at several positions.
Based on your knowledge of membrane structure and your knowledge of factors that determine whether a molecule can permeate a membrane or not by simple diffusion, suggest whether the pink pigment molecule in rhubarb stalks is water soluble or lipid soluble. Justify your choice.
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I don't exactly know how to structure this response. I understand that its water soluble because of the sugar molecules containing the OH group but I'm not sure if I need to refer to membrane structure and simple diffusion.
Help is appreciated 
Questions like this annoy me a bit - it does indeed seem as though there is no need for them to ask you to refer to such things as the membrane etc., but seeing as they've mentioned it, I suppose you'd really want to do so anyway in order to attain full marks.
they've mentioned that it is "relatively large" which appears to defy one of the fundamental criterion for simple diffusion..
You're on the money in saying that the properties of the carbohydrates give it polarity, leading to water solubility (although I wonder, does the fact that the sugars are attached to the presumably-non-carbohydrate hydrocarbon-rings have any effect on the molecule's water solubility?)
I'm thinking aloud here as I'm not sure yet, but perhaps the text you've cited gives us a membrane-transport-related clue as to why the molecule would not be able to pass thtrough, and hence that tells us that the molecule is indeed water soluble (e.g.,
if it's stored in the vacuole (which is membrane-bound), it can't be lipophilic as then it couldn't be stored )
EDIT: The more I think about it, the more I think that the bit I've bolded is the key point here (other than of course the polarity of the carbs)