Looking for someone to lead me on the path to answering this:
Pyrolusite, an ore of manganese, contains manganese in the form of MnO2. A sample of pyrolusite from a newly
discovered deposit is analysed to determine the degree of purity of the deposit.
To determine the amount of Mn in the pyrolusite sample, 1.25 g of dried pyrolusite was heated with 100 mL of
0.150 M oxalic acid (H2C2O4). The oxalic acid was in excess, so that all of the MnO2 reacted according to:
MnO2(s) + H2C2O4(aq) + 2H+(aq) → Mn2+(aq) + 2CO2(g) + 2H2O(l)
20.00 mL of the resulting solution is then titrated with an 0.0510 M solution of the triiodide ion
I3–(aq) + H2C2O4(aq) → 2CO2(g) + 2H+(aq) + 3I–(aq)
22.00 mL of the 0.0510 M triiodide solution was needed to react with the remaining oxalic acid.
a) Calculate the amount in mol of oxalic acid remaining original 100ml of solution after the pyrolusite had been reacted with the oxalic acid.
b) Calculate the amount in mol of oxalic acid used to reduce the MnO2 n the 1.25g of pyrolusite
c) Calculate the amount in mol of MnO present in the original 1.25g of pyrolusite and hence the percentage of MnO2 by mass present n the pyrolusite
Just a bit of guidance is required, but if your keen show
some of the working

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