Hey guys,
I am stuck on Q18 of the 2012 HSC Paper.
Which of the following changes take place when 50 ml of water is added to 50ml of 0.1 mol/L acetic acid? The answer is pH increases and degree of ionisation increases.
I don't understand why ionisation increases. Wouldn't this then mean that ph will decrease?
Thanks
Hey! It's a really good question, and quite a tough one too. Firstly, we need to remember that
ionisation is the removal of a hydrogen ion. For weak acids, like acetic acid, this will only occur a small percentage of the time. If we add more water,
more acid ions/hydrogen ions will dissociate. This means that the ionisation increases, just because it has more water to react with!
So, we know that there are MORE hydrogen ions in the solution after we add water than before. Why doesn't the pH change? Remember that the formula for pH is -log[H], where [H] is the CONCENTRATION of Hydrogen ions. Whilst the AMOUNT of Hydrogen ions have increased, the amount of liquid has doubled too. Ionisation will only barely increase, so the relative concentration of ions will actually decrease. As such, the concentration of Hydrogen ions will decrease, and thus the pH will increase.
Let me know if this explanation makes sense!
Jake