I'm not entirely sure where you want to see these exact values, so I'll do my best here.
If you want those little lines on the x-axis to be in increments of pi or pi/2 rather than 1, you can double-click on that number 1 sitting just below the x-axis near the origin and type in pi or pi/2 (or whatever is convenient) and click enter. This should make it much easier to identify irrational key points, especially the x-axis intercepts.
If you want the co-ordinates that appear on the screen when using the trace function or when finding zeroes or intersection points to appear as exact values, there is a way to do it, except it's a bit annoying and not really helpful if you are trying to find some unknown non-integer value and the other co-ordinate in the pair is either unknown or an integer. If this is what you are looking for, I can explain how to do this but its use is rather limited.