I like to imagine a speed vs. time graph for these sorts of questions, where the area is the distance. You have to realize that the time taken for the policeman to catch up is ‘x’ and that the policeman isn't just constantly accelerating; he gets to 100km/hr in two parts: first to 80km/hr in ten seconds and then to 100km/hr in another five. To find ‘x’, we need to find when both their distances traveled are equal (I think that is what you’re trying to do as well).
*We'll just say 80km/hr = 22.22m/s and 100km/hr = 27.78m/s
The car’s distance is easier to calculate as it is moving at a constant speed, so it is:

(distance = speed x time)
The policeman’s distance is slightly harder:
His distance from 0s-10s on the speed vs. time graph is marked by a triangle, so the distance for this section is:
/2 = 111.11 )
His distance from 10s-15s on the speed vs. time graph is marked by a sort of trapezium, so the distance for this section is:
*5/2 = 125)
And lastly, his distance from 15 seconds to the unknown 'x' seconds is:
)
From here, you have an overall equation that looks like this:
*27.78 + 111.11 + 125)



Sorry if this looks a bit cluttered, I'm a bit inexperienced with this...