The equation you've given me as well as the worded information is split in two ways:
1: The man is moving at a speed of 2km/h (which is 2/60 = 1/30 km per minute) for 45 mins.
2: The man is moving at a speed of 4km/h (which is 4/60 = 1/15 km per minute) for 30 mins.
Hence, logically, the first section of the equation would be about the first 45 mins of the man's travel, and the second section of the equation would be about the next 30 mins.
That is to say, the first section is 0 < t < 45, as t is dealing with minutes, and the next section is 45 < t < 45 + 30 = 45 < t < 75.
So we already know that c = 45 and e = 75.
The general formula for distance relative to speed and time is d = st. t in this case is the minutes elapsed and the distance is S(t), with it being expressed as km.
In the first section, we have S(t) = at. Logically we can see that S(t) is the "d" (distance), and t is the "t" (time) so a would then be the speed. Because S(t) is expressed in km while t is expressed in mins, then a has to be expressed in km/min (the conversion has already been done above. Hence, a = 1/30.
The next section, we have S(t) = bt +d. Remember that this is where 45 < t < 75 (i.e. when the guy is running). We know that S(t) is the speed in km and t is the time in minutes. Because the man, in this section, has already travelled for 45 mins under a speed of 1/30 km/min (i.e. has already completed the walking), hence we need to add the distance he travelled whilst walking to the equation, which is 1/30 * 45 = 3/2. So d = 3/2. That leaves b to be the speed he is travelling in the second section, which has to be in km/min (converted above). Hence b = 1/15.