errors is easy...

in gravimetric stuff like:
-loss of ions through transfer
-other ions could have reacted to form the precipitate
-some of the precipitate may have been lost in the filtrate
-the reaction was not complete
-the precipitate was not dried to constant mass
like someone else said, blah, blah, blah. and hence why these techniques are stupid and aren't even used anymore.
for volumetric it's important you know what will happen if:
-the burette, pipette and volumetric flask are rinsed with the wrong solution
-errors caused by misreading of the miniscus on calibration marks
-major source of error being the subjective observation of the end point according to the colour change.
pretty simple stuff....