This is so confusing. In electrolysis batteries function to pull e's from the reductant and supply it to the oxidant. The conversion is electrical to chemical, now where is this electrical energy stored in chemical? If you say as the oxidant uses e's then how come the energy conversion in Galvanic, the conversion is chemical to electrical? As in both cases, e's are consumed (stored)
ok im a little confused on what your asking
but let me try to give you a overview of how i see it and hopefully you will get it.
in galvanic cells
we are putting in electrical energy ( from the power source) and getting out chemical energy and heat ( THE TEMP RISES)
in galvanic cells . the reactions are SPONTANEOUS , that is . they do not need extra "force" for the electrons to flow from annode to cathode.... therefore . the anode is negative and the cathode is positive .. ( anions( negetive ions) go to the annode , cations ( positive ions) to go the cathode).
keep inmind .. galvanic cells are exothermic ( mostly) .. and therefore ... just like all chemical reactions . the reactants want to get from high energy state .. to a low energy state . and so they react spontaneously..
however
in ELECTROLYTIC cells.
the power source FORCES the elctrons from the annode to the cathode.
it withdraws electrons .. and take them .. it is not spontaneous
therefore .... since the electrons are being FORCED out .. the annode becomes positive . .. and the cathode becomes negetive. . ( its the complete opposite to galvanic cells)
but
keep inmind
in electrolytic cells .. . we are putting in chemical energy ( chemical reactions)
and forcing the reaction to happen ... and getting electricitty out of it
some 1 plz correct me im wrong with anything
but thats the way i see it
i hope it helps
goodluck.
KEEP INMIND
IN ELECTROLYTIC AND IN GALVANIC CELLS
REDUCTION OCCURS AT CATHODE AND OXIDATION OCCURS AT ANNODE.
EDIT : also keep inmind .. electrolytic cells in most cases are like endothermic reactions ( there needs to be alot of energy supplied for it to work) and so . when they get to the higher state .. they will want to react spontaneously to get lower .. but we prevent this using a seperator . such as porous barrier "
goodluck