Login

Welcome, Guest. Please login or register.

July 17, 2025, 06:56:34 pm

Author Topic: Atomic Absorption question  (Read 755 times)  Share 

0 Members and 1 Guest are viewing this topic.

Ematuro

  • Victorian
  • Trendsetter
  • **
  • Posts: 178
  • Respect: 0
Atomic Absorption question
« on: March 07, 2011, 06:20:05 pm »
0
Why are light of different energies absorbed by different elements?

burbs

  • Victorian
  • Part of the furniture
  • *****
  • Posts: 1800
  • Fuck da police - Aristotle
  • Respect: +227
Re: Atomic Absorption question
« Reply #1 on: March 07, 2011, 06:23:51 pm »
0
I think it has to do with each element having a different wavelength emitted as it becomes excited.

DNAngel

  • Victorian
  • Forum Regular
  • **
  • Posts: 72
  • Dragon Warrior
  • Respect: +7
Re: Atomic Absorption question
« Reply #2 on: March 07, 2011, 06:52:07 pm »
0
Light of different energies that are absorbed by different elements, are the source of their uniqueness.

That is, each element has a 'fingerprint' in the electromagnetic spectrum, that distinguishes them from other elements.
Striving to achieve an ATAR of 85+

Subjects: English, Chemistry, Mathematical Methods (CAS), Economics and Further Mathematics

Russ

  • Honorary Moderator
  • Great Wonder of ATAR Notes
  • *******
  • Posts: 8442
  • Respect: +661
Re: Atomic Absorption question
« Reply #3 on: March 07, 2011, 06:55:16 pm »
0
Why are light of different energies absorbed by different elements?

Different elements have different sets of valence electrons in their subshells. The atom absorbs light and promotes one of those electrons to a higher energy level (excited state). Eventually the energy is released and the atom returns to the ground state. That's why it's different energies for different elements

huaxiadragon

  • Victorian
  • Trendsetter
  • **
  • Posts: 124
  • Life is like Tetris, You can't take it back
  • Respect: +31
Re: Atomic Absorption question
« Reply #4 on: March 07, 2011, 07:02:47 pm »
0
Why are light of different energies absorbed by different elements?

Each element has different number of electrons in its outer shell and they are situated in different orbitals. For light to be absorbed, the energy of the light needs to be EXACTLY the difference in energy of the ground state orbit and the excited state.

Since the electron configution of each element is different, the amount of energy each electron absorbs in order to reach excited orbit is different. So that answers your question
ATAR 2010: 98.15
Chemistry: 50

2011-2013 (UoM | Bachelor of Science | Electrical Systems Major)

2014-2015 (UoM | Master of Engineering | Electrical | First Class Honours)

2016-2017 (Graduate Electrical Engineer)

2017+ Senior Engineer (Electronic Maintenance)

My Personal Guide on How I studied to get a 50!
Huaxiadragon's Experience in getting a 50 in Chem (Guide to How I studied)

huaxiadragon

  • Victorian
  • Trendsetter
  • **
  • Posts: 124
  • Life is like Tetris, You can't take it back
  • Respect: +31
Re: Atomic Absorption question
« Reply #5 on: March 07, 2011, 07:03:54 pm »
0
oh man why do people reply ahead of me when I was typing?
ATAR 2010: 98.15
Chemistry: 50

2011-2013 (UoM | Bachelor of Science | Electrical Systems Major)

2014-2015 (UoM | Master of Engineering | Electrical | First Class Honours)

2016-2017 (Graduate Electrical Engineer)

2017+ Senior Engineer (Electronic Maintenance)

My Personal Guide on How I studied to get a 50!
Huaxiadragon's Experience in getting a 50 in Chem (Guide to How I studied)

Mao

  • CH41RMN
  • Honorary Moderator
  • Great Wonder of ATAR Notes
  • *******
  • Posts: 9181
  • Respect: +390
  • School: Kambrya College
  • School Grad Year: 2008
Re: Atomic Absorption question
« Reply #6 on: March 07, 2011, 07:04:20 pm »
0
Why are light of different energies absorbed by different elements?

Different elements have different sets of valence electrons in their subshells. The atom absorbs light and promotes one of those electrons to a higher energy level (excited state). Eventually the energy is released and the atom returns to the ground state. That's why it's different energies for different elements

Or rather, the subshells are all similarly configured, and electrons fill into the subshells in similar fashion, but the same subshell in different elements have slightly different energies due to the nucleus being different (different charge). This means transitions between subshells have energies unique to an element. Such transition is usually facilitated by absorption or emission of light (where energy is related to wavelength), thus the wavelengths absorbed is unique to an element (i.e. the color absorbed is unique).

@Huaxiadragon, similar correction, I wouldn't go so far as to say valence electrons are in 'different' orbitals. Electrons fill into orbitals in similar fashion (in fact, the ground state configuration is highly predictable). Emission lines/adsorption lines do not so much depend on where the electrons are, but more on the energy level of the orbitals, which change from element to element.
« Last Edit: March 07, 2011, 07:06:43 pm by Mao »
Editor for ATARNotes Chemistry study guides.

VCE 2008 | Monash BSc (Chem., Appl. Math.) 2009-2011 | UoM BScHon (Chem.) 2012 | UoM PhD (Chem.) 2013-2015