a) This question is essentially asking to find the mol of oxalic acid excess in 100ml of the original solution.
To find the mol of oxalic acid excess we must first find the mol of I3- (n=cv)
then using stoichiometry, n(oxalic acid in 20ml)=n(I3-)
then n(oxalic acid in 100ml)=n(oxalic acid in 20ml)*5/1
which gave me an answer of 0.00560 mol or 5.60*10^-3
b) This question is asking the mol of oxalic acid reacting with MnO2..
This is a back titration, so the mol of oxalic acid that reacted with MnO2
---> n(oxalic acid initially) - n(oxalic acid excess).
which gave me an answer of 0.00940 mol or 9.40*10^-3 mol
c) Here use stoichiometry to find the mol of MnO2. Then simply find the mass by
mass=mol*molar mass, then the percentage
which gave me an answer of 65.3%.
Hopefully i was helpful.