These identities work for all values of θ. To understand why, you can look at all the different possible cases. Ie: Try a value of θ in each quadrant.
If θ is in the 1st quadrant, sin and cos are both +ve.
Thus -θ will be in the 4th quadrant. In the 4th quadrant, sin is -ve but cos is +ve.
Since sin(θ) changes signs, but cos(θ) is still the same sign, the identities hold true.
If θ is in the 2nd quadrant, sin is +ve but cos is -ve.
Thus -θ will be in the 3rd quadrant. In the 3rd quadrant, sin and cos are both -ve.
Since sin(θ) changes signs, but cos(θ) is still the same sign, the identities hold true.
If θ is in the 3rd quadrant, sin and cos are both -ve.
Thus -θ will be in the 2nd quadrant. In the 2nd quadrant, sin is +ve but cos is -ve.
Since sin(θ) changes signs, but cos(θ) is still the same sign, the identities hold true.
If θ is in the 4th quadrant, sin is -ve but cos is +ve.
Thus -θ will be in the 1st quadrant. In the 1st quadrant, sin and cos are both +ve.
Since sin(θ) changes signs, but cos(θ) is still the same sign, the identities hold true.
Therefore, these identities hold true for all values of θ.