The first thing that comes to mind is when you start dealing with waves and standing waves in a mathematical sense in physics. You may have two waves that are interfering with each other that are out of phase, which is where the compound angle formulas can come in to help simplify the situation. Extending this to engineering, you can get forced oscillations problems where they'll come up and simplify the problem, turning a complex combination of sines and cosines into a simple form which is a hell of a lot easier to work with (talking turning 5 pages of work into about half a page).
Really later (talking uni level, which is most of what I'm talking about above) on you won't be using them to compare angles, but rather using them to help simplify situations where products of sine and cosine occur.
For spesh you might use them a bit later to get out of tricky situations in calculus, when you're trying to integrate something that looks awful, but has a much prettier and elegant look when you realise what you can turn it into, which in turn makes the solution a lot easier and nicer.
I guess also the derivation of cis uses them a bit to simplify things.
tl;dr, they're worth it, they get you out of ugly situations later on.