For 2.
On the left (2.5kg mass), there is a tension force (let's call it

) directly upwards, while there is a force of
2.5g N downwards.
Likewise, on the right (4.5 kg mass), there is also a tension force of

N directly upwards, while there is a force of
4.5g N downwards.
Since the right block is heavier, it is obvious that that the 4.5 kg mass will move downwards, while the 2.5 kg mass will move upwards (the pulley will turn clockwise). Thus I (personally) choose clockwise movement about the pulley to be positive. Also just for reference,

, where F is the
net force.
So for the 2.5 kg mass (which moves up),

[equation 1]
For the 4.5 kg mass (which moves down),

[equation 2]
Equating equations 1 and 2,


You can then find t by substituting a into either equation 1 or 2
EDIT: did a bit of editing lol