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April 04, 2026, 09:15:10 pm

Author Topic: Calibration factor equations  (Read 8513 times)  Share 

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simo101

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Calibration factor equations
« on: November 09, 2014, 12:45:20 pm »
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While I was writing down the calibration factor equations in my notes and trying to memorise them, I noticed that deltaH=mxcxdeltaT (where c is the specific heat capacity) and Cf=deltaH/deltaT. So therefore does Cf also = mc? As mc = deltaH/deltaT

Sorry if this is a stupid algebraic question but I can't find anything that proves this correct or incorrect

Yacoubb

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Re: Calibration factor equations
« Reply #1 on: November 09, 2014, 01:25:37 pm »
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While I was writing down the calibration factor equations in my notes and trying to memorise them, I noticed that deltaH=mxcxdeltaT (where c is the specific heat capacity) and Cf=deltaH/deltaT. So therefore does Cf also = mc? As mc = deltaH/deltaT

Sorry if this is a stupid algebraic question but I can't find anything that proves this correct or incorrect

The change in enthalpy is equal to energy/number of moles. McdeltaT is the energy, so it's in fact mcdeltaT/number of moles. Cf = Energy/T, not deltaT/T.

simo101

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Re: Calibration factor equations
« Reply #2 on: November 09, 2014, 06:48:42 pm »
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The change in enthalpy is equal to energy/number of moles. McdeltaT is the energy, so it's in fact mcdeltaT/number of moles. Cf = Energy/T, not deltaT/T.

But if the enthalpy= mass x Cp x deltaT and Cf= energy/deltaT, then shouldn't Cf = mass x Cp because if you move the equation energy = mass x Cp x DeltaT you get mass x Cp = energy/deltaT and energy/deltaT = Cf

Jason12

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Re: Calibration factor equations
« Reply #3 on: November 09, 2014, 06:56:12 pm »
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is the energy in these equations always in joules?
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simo101

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Re: Calibration factor equations
« Reply #4 on: November 09, 2014, 07:09:58 pm »
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is the energy in these equations always in joules?

Yes always in joules, I have found that is a common thing they test in the exams (ie put the calibration factor in kJdegreesC^-1 to try and catch people out)

speedy

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Re: Calibration factor equations
« Reply #5 on: November 09, 2014, 07:16:11 pm »
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is the energy in these equations always in joules?

For specific heat capacity, yes. CF can be kJ/mol etc.
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simo101

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Re: Calibration factor equations
« Reply #6 on: November 09, 2014, 07:32:03 pm »
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The change in enthalpy is equal to energy/number of moles. McdeltaT is the energy, so it's in fact mcdeltaT/number of moles. Cf = Energy/T, not deltaT/T.

Similarly E=VIt and Q=It so therefore Q also equals Q=E/V as E=QV.

I was wondering if I am allowed to alter the E=mass x Cp x deltaT equation like I have above.