Why can temperature only affect the equilibrium constant?
thanks!
The K constant is the ratio of products to reactants at a specific temperature.
When concentration/pressure changes, the ratio is out of balance, so the equilibrium will shift to minimise the change and re-establish that special ratio of products to reactants. When temperature changes, the equilibrium will shift to minimise that change in temperature and it will stay there, hence the K ratio is now changed as long as that temperature remains constant.
For example:
I have an exothermic reaction, and I increase the temperature from 400'C to 700'C and keep it there. The equilibrium will shift to the left to minimise the change but the position will stay there because it cannot forward react to the right since that's exothermic. hence, K is now changed.
Hope this explanation helps

Hi, can someone please help me with Q17 of the 2014 paper? thanks
https://www.boardofstudies.nsw.edu.au/hsc_exams/2014/pdf_doc/2014-hsc-chemistry.pdf

.}\\ \text{Total E=1.36V+(-0.16V)=1.2V, so it's A})
For the production of sulfuric acid why can’t water be added straight to SO3, why is oleum produced first?
The reaction between sulfur trioxide and water is very exothermic and will create a fine mist of sulfuric acid everywhere, which is both dangerous and hard to clean up. The reaction between oleum and water is less exothermic and is safer to use.
