I know it's already answered, but here is how I see part (a) and (b).
Part (a) asks for any two friends to win the prize; we're not necessarily saying who exactly will win the prize.
Consider these five people:
A, B, C, D, and E.
A is just as likely to win as B; B is just as likely to win as A, etc.
So, we know this is a binomial probability, selecting two of the five available people to be a winner.
Now, part (b) can be considered a conditional probability, in that we know one winner already. This means that Janette has a 100% chance at being chosen, yet she still has that 0.45 chance at winning. It might seem confusing at first, but when we specify that Janette won, we're only interested in choosing Janette and A, or Janette and B, or Janette and C, or Janette and D.
This means that there are four ways in selecting the second person to win (ie. this becomes a binomial probability in itself), which is what the solution says.