Why do we specifically use cold water in the prac to determine and compare the heat of combustion of alcohols?
The short answer is that
we don't. The formula only cares about the
change in temperature, so based on that the same amount of energy is required to raise water's temperature from 25 to 26 degrees as it takes to raise water's temperature from 89 to 90 degrees. So, we generally start with cold water and heat it up because that's just the
easiest thing to do. What's the alternative? Heat some water up using a hot plate, then do the experiment? Then, you'll encounter problems with determining the initial temperature accurately (as it continues to drop before more heat is applied), consistent heating of the liquid, heating of glassware and metal etc.
However, Rui also has a point. A heated system (in comparison to the environment around it) is more likely to cool, because the 'aim' of a system is to reach a single temperature. So, if we start with room temperature water, it will be very hard for it to cool down. However, water at 80 degrees can cool down much more easily, as the environment REALLY wants to suck up some of that heat. To be honest, I think this affect has very, very little impact on the experiment as a whole. I think my first answer is more pertinent to your question.