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October 12, 2025, 11:47:05 am

Author Topic: HSC Chemistry Question Thread  (Read 1292978 times)  Share 

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Mathew587

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Re: Chemistry Question Thread
« Reply #2775 on: September 19, 2017, 05:44:26 pm »
+7
Hi,
Does anyone have recent developments for polylactic acid? The online thing I found was something about improving crystallisation rates but I have no clue what it means. Where can I find more info, and should I switch to a different biopolymer if I can't find a development?

Use these notes:

1.2.6 Use available evidence to gather and present data from secondary sources and analyse
progress in the recent development and use of a named biopolymer. This analysis should name
the specific enzyme(s) used or organism used to synthesise the material and an evaluation of
the use or potential use of the polymer produced related to its properties

Biopolymers are naturally occurring polymers found in living organisms.
Biopol
This biopolymer is called PHBV (poly-3-hydroxybutyrate-poly-3-hydroxyvalerate).
It is a co-polymer of polyhydroxybutyrate (PHB) and polyhydroxyvalerate (PHV).
The monomer of PHB is 3-hydroxybutanoic acid (common name 3-hydroxybutyric acid).
The monomer of PHV is 3-hydroxypentanoic acid (common name 3-hydroxyvaleric acid).

Production:
  • This polymer is produced industrially by bacteria (Ralstonia eutrophus or Alcaligenes eutrophus) growing in tanks with a carbon-based food source, high in glucose or valeric acid.
    The bacteria manufacture the PHBV which is stored in their cell walls as granules for later us as an energy source.
    The polymer is then isolated and purified.

Uses in relation to properties:
  • Biopol is mainly used in medical applications (e.g. surgical stitches and tissue scaffolding) as it is biocompatible and biodegradable (products decompose naturally and no surgery is needed to remove them).
    The use of biopolymers in medicine will mean more lives can be saved due to biopolymer transplants and fewer allergic reactions.
    Biopol is also used to make disposable items (e.g. bottles, razors and shampoo containers) as it is biodegradable and non-toxic. However, this is uncommon now, due to the high cost of production.

Recent developments:
  • Recently, the gene for producing Biopol polymer strands from the Alcaligenes eutrophus bacteria was extracted and implanted into E. coli using genetic engineering techniques. E. coli bacteria are much easier to grow than other bacteria, and thus are cheaper.
    Scientists have also attempted to genetically engineer plants such as cress so that they produce biodegradable plastics rather than storing starch. This results in a much cheaper process, although it is still more expensive than petrochemical polymers.

Evaluation:
  • Biopol is currently much more expensive than petrochemical plastics, so research is being carried out to genetically modify bacteria to control the plastic that they form. There is a growing demand for it where biodegradability and biocompatibility are important.
    It has an advantage over petroleum-based polymers of being renewable, as it is formed from a microorganism. Biodegradable polymers may eventually replace petroleum-based polymers, reducing our dependence on fossil fuels and allowing them to last longer.
« Last Edit: September 19, 2017, 05:46:54 pm by Mathew587 »
HSC 2017- 90.58
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bsdfjnlkasn

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Re: Chemistry Question Thread
« Reply #2776 on: September 22, 2017, 07:30:24 pm »
+1
Hey there!

I was just wondering if aside from knowing the conditions necessary for fermentation to occur, we were required to justify them? :)

angelahchan

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Re: Chemistry Question Thread
« Reply #2777 on: September 22, 2017, 07:40:21 pm »
+6
Hey there!

I was just wondering if aside from knowing the conditions necessary for fermentation to occur, we were required to justify them? :)
Is this for the option or for the rest of the chemistry course? Because if you mean the conditions for fermentation of glucose to ethanol, there are questions where you're expected to explain/justify the conditions, although I can't think of one specifically. I think I did some questions asking why the reaction has to be done anaerobically.
Here's a table of the justifications from https://dc.edu.au/hsc-chemistry-production-of-materials/#Ethanol_A_renewable_resource

arunasva

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Re: Chemistry Question Thread
« Reply #2778 on: September 22, 2017, 10:58:23 pm »
+1
Hey there!

I was just wondering if aside from knowing the conditions necessary for fermentation to occur, we were required to justify them? :)


I have seen a question where they askedwhy did the rate of fermentation drop after an hour (or some period of time). Then you gotta recognize the condition affecting it and justify the statement  -  Alkanol increased and the poor yeast died off.   Other an' that I haven't seen any, where you justify the actual conditions.
:3

mary123987

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Re: Chemistry Question Thread
« Reply #2779 on: September 23, 2017, 09:45:34 am »
+1
Hey could someone please explain why the volume of gas never exceeds 380 ml for part question 22(b) , it is clear from the graph but im not sure what calculations to use to infer that Hcl is the limiting factor and that Zn is in excess.
http://www.boardofstudies.nsw.edu.au/hsc_exams/hsc2005exams/pdf_doc/chemistry_05.pdf
Regards
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Natasha.97

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Re: Chemistry Question Thread
« Reply #2780 on: September 23, 2017, 10:03:15 am »
+5
Hey could someone please explain why the volume of gas never exceeds 380 ml for part question 22(b) , it is clear from the graph but im not sure what calculations to use to infer that Hcl is the limiting factor and that Zn is in excess.
http://www.boardofstudies.nsw.edu.au/hsc_exams/hsc2005exams/pdf_doc/chemistry_05.pdf
Regards

Hi!

No calculations are required for this question. In this case, hydrogen gas was produced when the amount of Zinc reached 1.22g. However, as more Zinc is added, the volume of gas remains the same. This is because all HCl has been used up; any additional Zinc that is added to the mixture does not have any HCl to react with. Therefore, HCl is the limiting factor (as it limits the volume of H2 produced), and Zn is in excess (in this case, in excess of 0.71g).

Hope this helps

« Last Edit: September 23, 2017, 10:28:54 am by Jess1113 »
Life is weird and crazy as heck but what can you do?

mary123987

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Re: Chemistry Question Thread
« Reply #2781 on: September 23, 2017, 10:11:13 am »
+1
Hi!

No calculations are required for this question. In this case, hydrogen gas was produced when the amount of Zinc reached 1.22g. However, as more Zinc is added, the volume of gas remains the same. This is because all HCl has been used up; any additional Zinc that is added to the mixture does not have any HCl to react with. Therefore, HCl is the limiting factor (as it limits the volume of H2 produced), and Zn is in excess (in this case, in excess of 0.73g).

Hope this helps


Hey thanks alot ,just wondering if you weren't given the table how would you know when all the HCl was used up? and how did you calculate that Zn was in excess by 0.73 g thanks heaps
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angelahchan

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Re: Chemistry Question Thread
« Reply #2782 on: September 23, 2017, 10:37:38 am »
+4
Hey thanks alot ,just wondering if you weren't given the table how would you know when all the HCl was used up? and how did you calculate that Zn was in excess by 0.73 g thanks heaps

Hey thanks alot ,just wondering if you weren't given the table how would you know when all the HCl was used up? and how did you calculate that Zn was in excess by 0.73 g thanks heaps

The zinc is in excess because by 1.22 g the vol of gas doesn't increase, thus when 1.93 g of zinc is added in, there's 0.71 g of excess (I think she corrected it)
I don't think you're able to calculate when it would be used up if you were only given data up to 1.22g, because we aren't given the concentration of the HCl. This means we don't know if the moles of HCl are insufficient to react with  the moles of zinc in a 2:1 ratio.

Mod edit: ratio changed as requested :)
« Last Edit: September 23, 2017, 11:05:09 am by Jess1113 »

Natasha.97

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Re: Chemistry Question Thread
« Reply #2783 on: September 23, 2017, 10:39:36 am »
+5
Hey thanks alot ,just wondering if you weren't given the table how would you know when all the HCl was used up? and how did you calculate that Zn was in excess by 0.73 g thanks heaps

Hi!

If the graph was given, it should look something like this:



The HCl is used up when the graph starts to level off, which shows that the volume of hydrogen gas doesn't increase when more Zinc is being added to the mixture. Excess should be 0.71g :)
Life is weird and crazy as heck but what can you do?

mary123987

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Re: Chemistry Question Thread
« Reply #2784 on: September 23, 2017, 10:42:35 am »
+1
Hi!

If the graph was given, it should look something like this:

(Image removed from quote.)

The HCl is used up when the graph starts to level off, which shows that the volume of hydrogen gas doesn't increase when more Zinc is being added to the mixture. Excess should be 0.71g :)
The zinc is in excess because by 1.22 g the vol of gas doesn't increase, thus when 1.93 g of zinc is added in, there's 0.71 g of excess (I think she corrected it)
I don't think you're able to calculate when it would be used up if you were only given data up to 1.22g, because we aren't given the concentration of the HCl. This means we don't know if the moles of HCl are insufficient to react with  the moles of zinc in a 1:1  ratio.
Thanks so much it makes alot of sense im glad you cant be expected to calculate when it is used up
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angelahchan

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Re: Chemistry Question Thread
« Reply #2785 on: September 23, 2017, 10:55:30 am »
+2
Thanks so much it makes alot of sense im glad you cant be expected to calculate when it is used up

idk why the "modify message" thing isn't working, just wanted to correct myself that it's a 1:2 ratio of zinc:HCl, not 1:1

mylinh-nguyen

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Re: Chemistry Question Thread
« Reply #2786 on: September 23, 2017, 09:52:23 pm »
+1
(a) Why is the calculated concentration of the standardised NaOH solution different 2 from the concentration calculated using the mass given, assuming no human error occurred?
(b) Determine the concentration of citric acid in the lemon cordial.

I'm so confused please help

Eric11267

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Re: Chemistry Question Thread
« Reply #2787 on: September 23, 2017, 09:59:14 pm »
+2
(a) Why is the calculated concentration of the standardised NaOH solution different 2 from the concentration calculated using the mass given, assuming no human error occurred?
(b) Determine the concentration of citric acid in the lemon cordial.

I'm so confused please help
I do VCE Chemistry so please take what I say with a grain of salt.
To my knowledge, NaOH reacts with carbon dioxide in the air so the amount you put in isn't the same as the amount in solution.
For part b, I'm assuming you use the results of titrating HCl to determine the concentration of the NaOH solution and use those results to determine the concentration of citric acid

MisterNeo

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Re: Chemistry Question Thread
« Reply #2788 on: September 23, 2017, 10:18:46 pm »
+8
(a) Why is the calculated concentration of the standardised NaOH solution different 2 from the concentration calculated using the mass given, assuming no human error occurred?
(b) Determine the concentration of citric acid in the lemon cordial.

I'm so confused please help

Sodium hydroxide in solid form is hygroscopic and will absorb moisture from the air. This may be why the calculations are off.

For Part B calculations: :)
« Last Edit: September 23, 2017, 10:45:21 pm by MisterNeo »

mylinh-nguyen

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Re: Chemistry Question Thread
« Reply #2789 on: September 23, 2017, 11:46:40 pm »
+1
Sodium hydroxide in solid form is hygroscopic and will absorb moisture from the air. This may be why the calculations are off.

For Part B calculations: :)
(Image removed from quote.)
thank youu soo much!!